Wide-Angle X-ray Diffraction Evidence of Structural Coherence in CsPbBr₃ Nanocrystal Superlattices.

ABSTRACT: Films made of colloidal CsPbBr₃ nanocrystals packed in isolated or densely-packed superlattices display a remarkably high degree of structural coherence. The structural coherence is revealed by the presence of satellite peaks accompanying Bragg reflections in wide-angle X-ray diffraction experiments in parallel-beam reflection geometry. The satellite peaks, also called "superlattice reflections", arise from the interference of X-rays diffracted by the atomic planes of the orthorhombic perovskite lattice. The interference is due to the precise spatial periodicity of the nanocrystals separated by organic ligands in the superlattice. The presence of satellite peaks is a fingerprint of the high crystallinity and long-range order of nanocrystals, comparable to those of multilayer sup

SUBMITTER: Toso S 

PROVIDER: S-EPMC7497715 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature