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Self-Lifting NaCl Crystals.

ABSTRACT: We show that macroscopic crystals of NaCl that form from evaporating drops of aqueous salt solutions can spontaneously lift themselves up and away from a hydrophobic surface. At the end of the evaporation process, tiny crystals of NaCl grow onto larger ones and form "legs" that push the large crystals away from the surface. The temperature dependence of the lifting speed is found to exhibit Arrhenius behavior with an activation energy similar to that of crystals growing in solution: the crystal growth itself determines the lifting speed that can be up to half a centimeter per minute. We show that surface hydrophobicity is a necessary but not a sufficient condition to obtain this "self-lifting" behavior.

SUBMITTER: Salim H

PROVIDER: S-EPMC7498147 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Self-Lifting NaCl Crystals.

Salim Herish H Kolpakov Paul P Bonn Daniel D Shahidzadeh Noushine N

The journal of physical chemistry letters 20200824 17

We show that macroscopic crystals of NaCl that form from evaporating drops of aqueous salt solutions can spontaneously lift themselves up and away from a hydrophobic surface. At the end of the evaporation process, tiny crystals of NaCl grow onto larger ones and form "legs" that push the large crystals away from the surface. The temperature dependence of the lifting speed is found to exhibit Arrhenius behavior with an activation energy similar to that of crystals growing in solution: the crystal ...[more]

PMID: 32787297

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