Dataset Information

CeO2-Based Two-Dimensional Layered Nanocomposites Derived from a Metal-Organic Framework for Selective Electrochemical Dopamine Sensors.

ABSTRACT: In this work, we demonstrate the incorporation of two-dimensional (2D) layered materials into a metal-organic framework (MOF) derived from one-dimensional (1D) cerium oxide (CeO2) for the electrochemical detection of dopamine. Ce-MOF was employed as a sacrificial template for preparing CeO2 with 2D materials by the pyrolysis process. The influence of the pyrolysis temperature was studied to achieve a better crystal structure of CeO2. Siloxene improved the dopamine sensing performance of CeO2 compared with graphitic carbon nitride (g-C3N4) due to the basal plane surface oxygen and hydroxyl groups of 2D siloxene. Under optimal conditions, the fabricated CeO2/siloxene electrode exhibited a detection limit of 0.292 ?M, with a linear range from 0.292 ?M to 7.8 ?M. This work provides a novel scheme for designing the CeO2 material with siloxene for excellent dopamine sensors, which could be extended towards other biosensing applications.

SUBMITTER: Ge C

PROVIDER: S-EPMC7506630 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature

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CeO2-Based Two-Dimensional Layered Nanocomposites Derived from a Metal-Organic Framework for Selective Electrochemical Dopamine Sensors.

Ge Chengjie C Ramachandran Rajendran R Wang Fei F

Sensors (Basel, Switzerland) 20200828 17

In this work, we demonstrate the incorporation of two-dimensional (2D) layered materials into a metal-organic framework (MOF) derived from one-dimensional (1D) cerium oxide (CeO2) for the electrochemical detection of dopamine. Ce-MOF was employed as a sacrificial template for preparing CeO2 with 2D materials by the pyrolysis process. The influence of the pyrolysis temperature was studied to achieve a better crystal structure of CeO2. Siloxene improved the dopamin ...[more]

PMID: 32872309

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Project description:Metal-organic frameworks (MOFs) have been an excellent platform for carbon dioxide reduction reactions (CO2RR). In this work, the feasibility of electrochemical reduction of CO2 to obtain C2-deep value-added products was investigated by the preparation of Mg-containing MOF-74 samples combined with transition metal cations (Ni2+, Co2+ and Zn2+). The prepared MOFs were used as electrocatalysts in CO2RR. Chronoamperometric analysis coupled to ATR-FTIR spectroscopy was employed to characterize the CO2 reduction products and subsequently via 1H NMR. Although an isostructural crystalline structure was observed in all synthesized MOFs, the pore diameter distribution was significantly affected due to the Mg coordination along with each transition metal nuclei with the organic ligand to form the MOF-74. Our results showed that Mg-containing MOF-74 electrocatalysts combined with Ni, Co and Zn ions successfully reduced CO2 to C2-deep products, while the monometallic Mg-MOF-74 showed only CO2 mineralization. An ester acetate, isopropyl alcohol, and formic acid were produced by Mg/Ni-MOF-74; isopropyl alcohol was provided by Mg/Co-MOF-74, and ethanol was generated by Mg/Zn-MOF-74. We observed that the change of the transition cation was a key factor in the selectivity of the obtained products, while the degree of Mg ions effectively incorporated into the MOF structure tuned the porosity and the electrocatalytic activity. Among them, Mg/Zn-MFOF-74 showed the highest Mg content loaded after synthesis and thus the most favorable electrocatalytic behavior towards CO2 reduction. Highlights • CO2-derived C2-deep reduction products were obtained by Mg-containing MOF-74 bimetallic electrocatalysts.• Mg-containing MOF-74 bimetallic electrocatalysts reduced CO2 to ester acetate, isopropanol, formic acid, and ethanol.• Mg/Zn-MOF-74 displayed the highest current density at a lower onset potential in CO2-saturated electrolyte.• The pore network could be tuned by the effective Mg content on a MOF-74 bimetallic sample.• Mg/Zn-MOF-74 showed the highest Mg content among all bimetallic electrocatalysts after the synthesis.

Dataset Information

CeO2-Based Two-Dimensional Layered Nanocomposites Derived from a Metal-Organic Framework for Selective Electrochemical Dopamine Sensors.

Publications

CeO<sub>2</sub>-Based Two-Dimensional Layered Nanocomposites Derived from a Metal-Organic Framework for Selective Electrochemical Dopamine Sensors.

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