Ontology highlight
ABSTRACT:
SUBMITTER: Naranjo T
PROVIDER: S-EPMC7508985 | biostudies-literature | 2020 Sep
REPOSITORIES: biostudies-literature
Naranjo Teresa T Álvarez-Asencio Rubén R Pedraz Patricia P Nieto-Ortega Belén B Silva Sara Moreno-Da SM Burzurí Enrique E Rutland Mark W MW Pérez Emilio M EM
Scientific reports 20200922 1
We show that H-bonded host-guest systems associate in ionic liquids (ILs), pure salts with melting point below room temperature, in which dipole-dipole electrostatic interactions should be negligible in comparison with dipole-charge interactions. Binding constants (K<sub>a</sub>) obtained from titrations of four H-bonded host-guest systems in two organic solvents and two ionic liquids yield smaller yet comparable K<sub>a</sub> values in ionic liquids than in organic solvents. We also detect the ...[more]