Ontology highlight
ABSTRACT:
SUBMITTER: Eaton MC
PROVIDER: S-EPMC7566828 | biostudies-literature | 2020 Apr
REPOSITORIES: biostudies-literature
Eaton Mary C MC Knight Brian J BJ Catalano Vincent J VJ Murray Leslie J LJ
European journal of inorganic chemistry 20200221 15-16
We report catalytic silylation of dinitrogen to tris(trimethylsilyl)amine by a series of trinuclear first row transition metal complexes (M = Cr, Mn, Fe, Co, Ni) housed in our tris(β-diketiminate) cyclophane (<b>L</b> <sup><b>3-</b></sup> ). Yields are expectedly dependent on metal ion type ranging from 14 to 199 equiv NH<sub>4</sub> <sup>+</sup>/complex after protonolysis for the Mn to Co congeners, respectively. For the series of complexes, the number of turnovers trend observed is Co > Fe > C ...[more]