Dataset Information

Adsorption capability of brewed tea waste in waters containing toxic lead(II), cadmium (II), nickel (II), and zinc(II) heavy metal ions.

ABSTRACT: Recently, the search for low-cost eco-friendly adsorbents has become one of the main objectives of researchers. The aim of this study was to test the removal of four heavy metals, namely lead (Pb), zinc (Zn), nickel (Ni) and cadmium (Cd), from a simulated watery solution using brewed tea waste as a potentially suitable adsorbent. The effects of pH levels (2.0-6.0), adsorbent amount (0.1-5.0 g), contact times (1-150 min.) were examined throughout the adsorption process. The results of the experiments showed that the heavy metals elimination yields had an inverse relationship with pH and a linear relationship between the other parameters. The optimum pH for the removal of the heavy metals was between 4.0 and 5.0 in the case of the brewed tea waste. Equilibrium times of 2, 10, 30 and 5 min were required for the adsorption of Pb, Zn, Ni, Cd onto Camellia sinensis, respectively. Based on the results of this study it can be said that brewed tea waste has a high potential to remove heavy metals from aqueous solutions. The maximum adsorption capacities were calculated as 1.197, 1.457, 1.163 and 2.468 mg/g, for Pb, Zn, Ni and Cd, respectively, by fitting the equilibrium data to the Langmuir isotherm model.

SUBMITTER: Celebi H

PROVIDER: S-EPMC7567786 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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Adsorption capability of brewed tea waste in waters containing toxic lead(II), cadmium (II), nickel (II), and zinc(II) heavy metal ions.

Çelebi Hakan H Gök Gülden G Gök Oğuzhan O

Scientific reports 20201016 1

Recently, the search for low-cost eco-friendly adsorbents has become one of the main objectives of researchers. The aim of this study was to test the removal of four heavy metals, namely lead (Pb), zinc (Zn), nickel (Ni) and cadmium (Cd), from a simulated watery solution using brewed tea waste as a potentially suitable adsorbent. The effects of pH levels (2.0-6.0), adsorbent amount (0.1-5.0 g), contact times (1-150 min.) were examined throughout the adsorption process. The results of the experim ...[more]

PMID: 33067532

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Project description:The efficient removal of toxic metals ions from chemical industry wastewater is considered problematic due to the existence of pollutants as mixtures in the aqueous matrix, thus development of advanced and effective treatment method has been identified as a panacea to the lingering problems of heavy metal pollution. In this study, KIAgNPs decorated MWCNTs nano adsorbent was developed using combination of green chemistry protocol and chemical vapor deposition techniques and subsequently characterized using UV-Vis, HRTEM, HRSEM, XRD, FTIR and XPS. The adsorptive efficiency of MWCNTs-KIAgNPs for the removal of Cr(VI), Ni(II), Fe(II), Cd(II) and physico-chemical parameters like pH, TDS, COD, BOD, nitrates, sulphates, chlorides and phosphates from chemical industrial wastewater was examined in both batch and fixed bed systems. The result exhibited successful deposition of KIAgNPs on the surface of MWCNTs as confirmed by the microstructures, morphology, crystalline nature, functional groups and elemental characteristics of the MWCNTs-KIAgNPs. Optimum batch adsorption parameters include; pH (3 for Cr(VI) and 6 for Ni(II), Fe(II) and Cd(II) ions), contact time (60 min), adsorbent dosage (40 mg) and temperature (318 K). The binding capacities were obtained as follows; Cr6+ (229.540 mg/g), Ni2+ (174.784 mg/g), Fe2+ (149.552) and Cd2+ (121.026 mg/g), respectively. Langmuir isotherm and pseudo-second order kinetic model best described the experimental data in batch adsorption, while the thermodynamic parameters validated the chemisorption and endothermic nature of the adsorption process. In continuous adsorption, the metal ions were effectively removed at low metal influent concentration, low flow rate and high bed depth, whereby the experimental data were designated by Thomas model. The high physico-chemical parameters in the wastewater were successfully treated in both batch and fixed bed systems to fall within WHO permissible concentrations. The adsorption/desorption study illustrated over 80% metal removal by MWCNTs-KIAgNPs even after 8th adsorption cycle. This study demonstrated excellent performance of MWCNTs-KIAgNPs for chemical industry wastewater treatment.

Dataset Information

Adsorption capability of brewed tea waste in waters containing toxic lead(II), cadmium (II), nickel (II), and zinc(II) heavy metal ions.

Publications

Adsorption capability of brewed tea waste in waters containing toxic lead(II), cadmium (II), nickel (II), and zinc(II) heavy metal ions.

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