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Synthesis and Solution Properties of a Novel Hyperbranched Polymer Based on Chitosan for Enhanced Oil Recovery.

ABSTRACT: A new type of chitosan-modified hyperbranched polymer (named HPDACS) was synthesized through the free-radical polymerization of surface-modified chitosan with acrylic acid (AA) and acrylamide (AM) to achieve an enhanced oil recovery. The optimal polymerization conditions of HPDACS were explored and its structure was characterized by Fourier-transform infrared spectroscopy, hydrogen nuclear magnetic resonance, and environmental scanning electron microscopy. The solution properties of HPDACS in ultrapure water and simulated brine were deeply studied and then compared with those of partially hydrolyzed polyacrylamide (HPAM) and a dendritic polymer named HPDA. The experimental results showed that HPDACS has a good thickening ability, temperature resistance, and salt resistance. Its viscosity retention rate exceeded 79.49% after 90 days of aging, thus meeting the performance requirements of polymer flooding. After mechanical shearing, the viscosity retention rates of HPDACS in ultrapure water and simulated brine were higher than those of HPAM and HPDA, indicating its excellent shear resistance and good viscoelasticity. Following a 95% water cut after preliminary water flooding, 0.3 pore volume (PV) and 1500 mg/L HPDACS solution flooding and extended water flooding could further increase the oil recovery by 19.20%, which was higher than that by HPAM at 10.65% and HPDA at 13.72%. This finding indicates that HPDACS has great potential for oil displacement.

SUBMITTER: Chen Q

PROVIDER: S-EPMC7570182 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Synthesis and Solution Properties of a Novel Hyperbranched Polymer Based on Chitosan for Enhanced Oil Recovery.

Chen Qingyuan Q Ye Zhongbin Z Tang Lei L Wu Tao T Jiang Qian Q Lai Nanjun N

Polymers 20200918 9

A new type of chitosan-modified hyperbranched polymer (named HPDACS) was synthesized through the free-radical polymerization of surface-modified chitosan with acrylic acid (AA) and acrylamide (AM) to achieve an enhanced oil recovery. The optimal polymerization conditions of HPDACS were explored and its structure was characterized by Fourier-transform infrared spectroscopy, hydrogen nuclear magnetic resonance, and environmental scanning electron microscopy. The solution properties of HPDACS in ul ...[more]

PMID: 32961938

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Project description:Expanding swept volume technology via continuous-phase polymer solution and dispersed-phase particle gel is an important technique to increase oil production and control water production in mature waterflooding reservoirs. However, problems such as the low viscosity retention rate, deep migration, and weak mobility control of conventional polymers, and the contradiction between migration distance of particle gel and plugging strength, restrict the long-term effectiveness of oil displacement agents and the in-depth sweep efficiency expanding capability in reservoirs. Combined with the technical advantages of polymer and particle gel, a novel controllable phase-transition polymer was developed and systematically studied to gain mechanistic insights into enhanced oil recovery for mature waterflooding reservoirs. To reveal the phase-transition mechanism, the molecular structure, morphology, and rheological properties of the controllable phase-transition polymer were characterized before and after phase transition. The propagation behavior of the controllable phase-transition polymer in porous media was studied by conducting long core flow experiments. Two-dimensional micro visualization and parallel core flooding experiments were performed to investigate the EOR mechanism from porous media to pore level. Results show that the controllable phase-transition polymer could change phase from dispersed-phase particle gel to continuous-phase solution with the prolongation of ageing time. The controllable phase-transition polymer exhibited phase-transition behavior and good propagation capability in porous media. The results of micro visualization flooding experiments showed that the incremental oil recovery of the controllable phase-transition polymer was highest when a particle gel and polymer solution coexisted, followed by a pure continuous-phase polymer solution and pure dispersed-phase particle gel suspension. The recovery rate of the novel controllable phase-transition polymer was 27.2% after waterflooding, which was 8.9% higher than that of conventional polymer, providing a promising candidate for oilfield application.

Project description:A new series of hyperbranched polymers consisting of fluorene-alt-carbazole as the branches and the three-dimensional-structured spiro[3.3]heptane-2,6-dispirofluorene (SDF) as the core were designed and synthesized by one-pot Suzuki coupling polycondensation. A phosphor group with broad full width at half maximum (FWHM) bis(1-phenyl-isoquinoline)(acetylacetonato)iridium(iii) (Ir(Brpiq)2acac, 0.08 mol%) as the red-light emitting unit and bis(2-(4-bromophenyl)-1-[6-(9-carbazolyl)hexyl]-imidazole)(2-(5-(4-fluorinated phenyl)-1,3,4-triazole)pyridine)iridium(iii) ((CzhBrPI)2Ir(fpptz)) as the green-light emitting unit were introduced into the backbones to obtain sunlight-style white-light emission by adjusting the feeding ratios of (CzhBrPI)2Ir(fpptz) (0.08 to 0.32 mol%). The results indicate the synthesized polymers show high thermal stabilities and good amorphous film morphology because of the hyperbranched structures. Besides, the lowest unoccupied molecular orbital (LUMO) levels of polymers were reduced and the electron injection was improved because of excellent electron-transporting ability of the triazole unit in the green group. The hyperbranched structures can effectively suppress the polymers' chain distortion and aggregation, and promote the incomplete Förster resonance energy transfer (FRET) efficiency from fluorene-alt-carbazole segments to Ir complex units. As a result, the devices with hyperbranched polymer light-emitting layers realize white light emission, and the optimized device also exhibits good electroluminescent (EL) performance with Commission Internationale de l'Eclairage (CIE) coordinates at (0.32, 0.31), a maximum luminance of 9054 cd m-2, a maximum current efficiency of 3.59 cd A-1 and a maximum Color Rendering Index (CRI) of 91. The hyperbranched polymers based on fluorene-alt-carbazole branches and a SDF core and high-efficiency phosphor groups with broad full width at half maximum are attractive candidates for sunlight-style white polymer light-emitting device.

Dataset Information

Synthesis and Solution Properties of a Novel Hyperbranched Polymer Based on Chitosan for Enhanced Oil Recovery.

Publications

Synthesis and Solution Properties of a Novel Hyperbranched Polymer Based on Chitosan for Enhanced Oil Recovery.

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