Dataset Information

Towards programmable friction: control of lubrication with ionic liquid mixtures by automated electrical regulation.

ABSTRACT: For mechanical systems in relative motion it would be fascinating if a non-mechanical stimulus could be used to directly control friction conditions. Therefore, different combinations of lubricants and external triggers for tribological influence have already been investigated. We show that when two metallic friction partners are lubricated with ionic liquid mixtures (ILM), consisting of long-chain cation and two different high charge/mass ratio anion containing ILs, the application of an electric impulse induces a permanent change of the frictional response. Such mixtures are able to alter the coefficient of friction (COF) to a greater extent, more accurately and faster than the respective single-component ILs. This change in the frictional properties is presumably due to changes in the externally induced electrical polarization at the surface, which influences the molecular adsorption, the exchange of adsorbed ions and their molecular orientation. The correlation between surface charges and friction can be used to control friction. This is achieved by implementing an electric tribo-controller which can adjust preset friction values over time. Programming friction in this way is a first step towards tribosystems that automatically adapt to changing conditions.

SUBMITTER: Gatti F

PROVIDER: S-EPMC7572367 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Towards programmable friction: control of lubrication with ionic liquid mixtures by automated electrical regulation.

Gatti Felix F Amann Tobias T Kailer Andreas A Baltes Norman N Rühe Jürgen J Gumbsch Peter P

Scientific reports 20201019 1

For mechanical systems in relative motion it would be fascinating if a non-mechanical stimulus could be used to directly control friction conditions. Therefore, different combinations of lubricants and external triggers for tribological influence have already been investigated. We show that when two metallic friction partners are lubricated with ionic liquid mixtures (ILM), consisting of long-chain cation and two different high charge/mass ratio anion containing ILs, the application of an electr ...[more]

PMID: 33077844

Similar Datasets

Project description:The formation of ionic liquid (IL) mixtures has been proposed as an approach to rationally fine-tune the physicochemical properties of ILs for a variety of applications. However, the effects of forming such mixtures on the resultant properties of the liquids are only beginning to be understood. Towards a more complete understanding of both the thermodynamics of mixing ILs and the effect of mixing these liquids on their structures and physicochemical properties, the spatial arrangement and free volume of IL mixtures containing the common [C4C1im]+ cation and different anions have been systematically explored using small angle X-ray scattering (SAXS), positron annihilation lifetime spectroscopy (PALS) and 129Xe NMR techniques. Anion size has the greatest effect on the spatial arrangement of the ILs and their mixtures in terms of the size of the non-polar domains and inter-ion distances. It was found that differences in coulombic attraction between oppositely charged ions arising from the distribution of charge density amongst the atoms of the anion also significantly influences these inter-ion distances. PALS and 129Xe NMR results pertaining to the free volume of these mixtures were found to strongly correlate with each other despite the vastly different timescales of these techniques. Furthermore, the excess free volumes calculated from each of these measurements were in excellent agreement with the excess volumes of mixing measured for the IL mixtures investigated. The correspondence of these techniques indicates that the static and dynamic free volume of these liquid mixtures are strongly linked. Consequently, fluxional processes such as hydrogen bonding do not significantly contribute to the free volumes of these liquids compared to the spatial arrangement of ions arising from their size, shape and coulombic attraction. Given the relationship between free volume and transport properties such as viscosity and conductivity, these results provide a link between the structures of IL mixtures, the thermodynamics of mixing and their physicochemical properties.

Dataset Information

Towards programmable friction: control of lubrication with ionic liquid mixtures by automated electrical regulation.

Publications

Towards programmable friction: control of lubrication with ionic liquid mixtures by automated electrical regulation.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets