Ontology highlight
ABSTRACT:
SUBMITTER: Li Q
PROVIDER: S-EPMC7576827 | biostudies-literature | 2020 Oct
REPOSITORIES: biostudies-literature
Li Qizhao Q Li Chengjie C Baryshnikov Glib G Ding Yubin Y Zhao Chengxi C Gu Tingting T Sha Feng F Liang Xu X Zhu Weihua W Wu Xinyan X Ågren Hans H Sessler Jonathan L JL Xie Yongshu Y
Nature communications 20201020 1
Directly linked porphyrin dimers have attracted considerable attention because of their intriguing electronic features. Most emphasis has been placed on either dimers with large dihedral angles between the constituent planar monomeric subunits or those with overall planarity, referred to as "Planar-Twisted-Planar" and "Planar-Planar-Planar", respectively. Herein, we report a "Twisted-Planar-Twisted" framework, the hexaphyrin dimer D that exists in a trans configuration. Treatment of D with MeOH ...[more]