Dataset Information

Controllable and Diversiform Topological Morphologies of Self-Assembling Supra-Amphiphiles with Aggregation-Induced Emission Characteristics for Mimicking Light-Harvesting Antenna.

ABSTRACT: Controllable construction of diversiform topological morphologies through supramolecular self-assembly on the basis of single building block is of vital importance, but still remains a big challenge. Herein, a bola-type supra-amphiphile, namely DAdDMA@2?-CD, is rationally designed and successfully prepared by typical host-guest binding ?-cyclodextrin units with an aggregation-induced emission (AIE)-active scaffold DAdDMA. Self-assembling investigation reveals that several morphologies of self-assembled DAdDMA@2?-CD including leaf-like lamellar structure, nanoribbons, vesicles, nanofibers, helical nanofibers, and toroids, can be straightforwardly fabricated by simply manipulating the self-assembling solvent proportioning and/or temperature. To the best of knowledge, this presented protocol probably holds the most types of self-assembling morphology alterations using a single entity. Moreover, the developed leaf-like lamellar structure performs well in mimicking the light-harvesting antenna system by incorporating with a Förster resonance energy transfer acceptor, providing up to 94.2% of energy transfer efficiency.

SUBMITTER: Fu S

PROVIDER: S-EPMC7578885 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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Controllable and Diversiform Topological Morphologies of Self-Assembling Supra-Amphiphiles with Aggregation-Induced Emission Characteristics for Mimicking Light-Harvesting Antenna.

Fu Shuang S Su Xiang X Li Meng M Song Shanliang S Wang Lei L Wang Dong D Tang Ben Zhong BZ

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20200923 20

Controllable construction of diversiform topological morphologies through supramolecular self-assembly on the basis of single building block is of vital importance, but still remains a big challenge. Herein, a bola-type supra-amphiphile, namely DAdDMA@2<i>β</i>-CD, is rationally designed and successfully prepared by typical host-guest binding <i>β</i>-cyclodextrin units with an aggregation-induced emission (AIE)-active scaffold DAdDMA. Self-assembling investigation reveals that several morpholog ...[more]

PMID: 33101876

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Project description:Integration of plasmonic nanoantennas with catalytically active reactors in deliberately designed hybrid supra-nanostructures creates a dual-functional materials platform, based upon which precise modulation of catalytic reaction kinetics becomes accomplishable through optical excitations of plasmon resonances. Here, we have developed a multistep synthetic approach that enables us to assemble colloidal Au@C/Pt core@shell/satellite supra-nanostructures, in which the Au core functions as a light-harvesting plasmonic nanoantenna, the Pt satellites act as catalytically active reactors, and the C shell serves as a nanoscale dielectric spacer separating the reactors from the antenna, respectively. By adjusting several synthetic parameters, the size of the Au core, the thickness of the C shell, and the surface coverage of Pt satellites can all be tuned independently. Choosing Pt-catalyzed cascade oxidation of 3,3',5,5'-tetramethylbenzidine in an aerobic aqueous environment as a model reaction, we have systematically studied the detailed kinetic features of the catalytic reactions both in the dark and under visible light illumination over a broad range of reaction conditions, which sheds light on the interplay between plasmonic and catalytic effects in these antenna-reactor nanohybrids. The plasmonic antenna effect can be effectively harnessed to kinetically modulate multiple crucial steps during the cascade reactions, benefiting from plasmon-enhanced interband electronic transitions in the Pt satellites and plasmon-enhanced intramolecular electronic excitations in chromogenic intermediate species. In addition to the plasmonic antenna effect, photothermal transduction derived from plasmonic excitations can also provide significant contributions to the kinetic enhancements under visible light illumination. The knowledge gained from this work serves as important guiding principles for rational design and structural optimization of plasmonic antenna-reactor hybrid nanomaterials, endowing us with enhanced capabilities to kinetically modulate targeted catalytic/photocatalytic molecule-transforming processes through light illumination.

Dataset Information

Controllable and Diversiform Topological Morphologies of Self-Assembling Supra-Amphiphiles with Aggregation-Induced Emission Characteristics for Mimicking Light-Harvesting Antenna.

Publications

Controllable and Diversiform Topological Morphologies of Self-Assembling Supra-Amphiphiles with Aggregation-Induced Emission Characteristics for Mimicking Light-Harvesting Antenna.

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