Browse
Submit Data
Databases
API
Help

Dataset Information

20 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Electronic Skin from High-Throughput Fabrication of Intrinsically Stretchable Lead Zirconate Titanate Elastomer.

ABSTRACT: Electronic skin made of thin, soft, stretchable devices that can mimic the human skin and reconstruct the tactile sensation and perception offers great opportunities for prosthesis sensing, robotics controlling, and human-machine interfaces. Advanced materials and mechanics engineering of thin film devices has proven to be an efficient route to enable and enhance flexibility and stretchability of various electronic skins; however, the density of devices is still low owing to the limitation in existing fabrication techniques. Here, we report a high-throughput one-step process to fabricate large tactile sensing arrays with a sensor density of 25 sensors/cm² for electronic skin, where the sensors are based on intrinsically stretchable piezoelectric lead zirconate titanate (PZT) elastomer. The PZT elastomer sensor arrays with great uniformity and passive-driven manner enable high-resolution tactile sensing, simplify the data acquisition process, and lower the manufacturing cost. The high-throughput fabrication process provides a general platform for integrating intrinsically stretchable materials into large area, high device density soft electronics for the next-generation electronic skin.

SUBMITTER: Liu Y

PROVIDER: S-EPMC7586250 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Facile fabrication of polyurethane-based graphene foam/lead zirconate titanate/polydimethylsiloxane composites with good damping performance.

Project description:In modern society, much more noise and vibration are produced in traffic and industrial systems, which is harmful to human health, equipment safety and the environment, therefore damping materials are becoming increasingly important. A piezoelectric damping composite could broaden the damping temperature range and enhance the damping loss factor simultaneously by introducing a dissipation route of mechanical to electrical to heat energy. In this paper, a novel piezo-damping polyurethane-based graphene foam (PGF)/PZT/PDMS composite (PGPP) was facilely fabricated using a one-step vacuum-assisted filling method. Using three-dimensional graphene foam as a conductive phase, and due to its three-dimensional network structure, the PGPP composite can reach the percolation threshold with a dramatically reduced amount of RGO sheets. The effects of PZT content and frequency on the damping properties of the PGPP composites were investigated, and the results show that the storage modulus, loss modulus and loss factor of the PGPPs are all greatly enhanced compared to those of the PDMS matrix. Due to their flexibility, the PGPP composites can be used as good surface coating damping materials over a wide temperature range at different frequencies.

| S-EPMC9078480 | biostudies-literature

Pure Piezoelectricity Generation by a Flexible Nanogenerator Based on Lead Zirconate Titanate Nanofibers.

Project description:Lead zirconate titanate (PbZr0.52Ti0.48O3, PZT) alloys have been extensively studied to be used for piezoelectric nanogenerators to harvest energy from mechanical motions. In this study, PZT nanofiber-based nanogenerators were fabricated to test their true piezoelectric performance without the triboelectric effect. Aligned PZT nanofibers were fabricated by a sol-gel electrospinning process. The thickness, area, and orientation of the PZT textile made by electrospinning a PZT solution onto multipair metal wires or metal mesh were controlled to form a composite textile. After the calcination, the PZT textile mixed with polydimethylsiloxane was placed between two flexible indium-doped tin oxide-polyethylene naphthalate substrates. The performance parameters of the nanogenerators were investigated under the bending motion, which excludes the triboelectric effect. An assembled nanogenerator of an area of 8 cm2 and a thickness of 80 μm could generate an electrical output voltage of 1.1 V and a current of 1.4 μA under the bending strain. The piezoelectric voltage depended on the thickness of the PZT textile, whereas the piezoelectric current depended on both the thickness and the area of the PZT textile. The electrical performance of the device was significantly affected by the orientation of the PZT fiber and the bending direction. The output voltage and the output current were strain-dependent, whereas the total integrated charge was independent of the strain rate. The properties of the flexible nanogenerator could be quantified to verify the pure piezoelectric performance of the device.

| S-EPMC6648344 | biostudies-literature

Unexpectedly high piezoelectricity of Sm-doped lead zirconate titanate in the Curie point region.

Project description:Large piezoelectric coefficients in polycrystalline lead zirconate titanate (PZT) are traditionally achieved through compositional design using a combination of chemical substitution with a donor dopant and adjustment of the zirconium to titanium compositional ratio to meet the morphotropic phase boundary (MPB). In this work, a different route to large piezoelectricity is demonstrated. Results reveal unexpectedly high piezoelectric coefficients at elevated temperatures and compositions far from the MPB. At temperatures near the Curie point, doping with 2 at% Sm results in exceptionally large piezoelectric coefficients of up to 915?pm/V. This value is approximately twice those of other donor dopants (e.g., 477?pm/V for Nb and 435?pm/V for La). Structural changes during the phase transitions of Sm-doped PZT show a pseudo-cubic phase forming ?50?°C below the Curie temperature. Possible origins of these effects are discussed and the high piezoelectricity is posited to be due to extrinsic effects. The enhancement of the mechanism at elevated temperatures is attributed to the coexistence of tetragonal and pseudo-cubic phases, which enables strain accommodation during electromechanical deformation and interphase boundary motion. This work provides insight into possible routes for designing high performance piezoelectrics which are alternatives to traditional methods relying on MPB compositions.

| S-EPMC5841290 | biostudies-literature

Large Electrocaloric Effect in Relaxor Ferroelectric and Antiferroelectric Lanthanum Doped Lead Zirconate Titanate Ceramics.

Project description:Both relaxor ferroelectric and antiferroelectric materials can individually demonstrate large electrocaloric effects (ECE). However, in order to further enhance the ECE it is crucial to find a material system, which can exhibit simultaneously both relaxor ferroelectric and antiferroelectric properties, or easily convert from one into another in terms of the compositional tailoring. Here we report on a system, in which the structure can readily change from antiferroelectric into relaxor ferroelectric and vice versa. To this end relaxor ferroelectric Pb0.89La0.11(Zr0.7Ti0.3)0.9725O3 and antiferroelectric Pb0.93La0.07(Zr0.82Ti0.18)0.9825O3 ceramics were designed near the antiferroelectric-ferroelectric phase boundary line in the La2O3-PbZrO3-PbTiO3 phase diagram. Conventional solid state reaction processing was used to prepare the two compositions. The ECE properties were deduced from Maxwell relations and Landau-Ginzburg-Devonshire (LGD) phenomenological theory, respectively, and also directly controlled by a computer and measured by thermometry. Large electrocaloric efficiencies were obtained and comparable with the results calculated via the phenomenological theory. Results show great potential in achieving large cooling power as refrigerants.

| S-EPMC5366905 | biostudies-literature

Strongly Enhanced Piezoelectric Response in Lead Zirconate Titanate Films with Vertically Aligned Columnar Grains.

Project description:Pb(Zr0.52Ti0.48)O3 (PZT) films with (001) orientation were deposited on Pt(111)/Ti/SiO2/Si(100) substrates using pulsed laser deposition. Variation of the laser pulse rate during the deposition of the PZT films was found to play a key role in the control of the microstructure and to change strongly the piezoelectric response of the thin film. The film deposited at low pulse rate has a denser columnar microstructure, which improves the transverse piezoelectric coefficient (d31f) and ferroelectric remanent polarization (Pr), whereas the less densely packed columnar grains in the film deposited at high pulse rates give rise to a significantly higher longitudinal piezoelectric coefficient (d33f) value. The effect of film thickness on the ferroelectric and piezoelectric properties of the PZT films was also investigated. With increasing film thickness, the grain column diameter gradually increases, and also the average Pr and d33f values become larger. The largest piezoelectric coefficient of d33f = 408 pm V-1 was found for a 4-μm film thickness. From a series of films in the thickness range 0.5-5 μm, the z-position dependence of the piezoelectric coefficient could be deduced. A local maximum value of 600 pm V-1 was deduced in the 3.5-4.5 μm section of the thickest films. The dependence of the film properties on film thickness is attributed to the decreasing effect of the clamping constraint imposed by the substrate and the increasing spatial separation between the grains with increasing film thickness.

| S-EPMC5364435 | biostudies-literature

Phase Evolution, Filler-Matrix Interactions, and Piezoelectric Properties in Lead Zirconate Titanate (PZT)-Filled Polymer-Derived Ceramics (PDCs).

Project description:PZT-silsesquioxane-based 0-3 hybrid materials are prepared by mixing lead zirconate titanate (Pb(Zr,Ti)O3; PZT) powder with a [R-SiO3/2]n (R = H, CH3, CH=CH2, C6H5) silsequioxane preceramic polymer. A PZT load up to 55 vol.% can be reached in the final composite. The piezoelectric and mechanical properties are investigated as a function of the filler content and are compared with theoretical models and reference samples made of the pure preceramic polymer or PZT filler. The piezoelectric response of the composites, as expressed by the relative permittivity and the piezoelectric coefficients d33 and g33, increases with an increasing PZT content. The bending strength of the composites ranges between 15 MPa and 31 MPa without a clear correlation to the filler content. The thermal conductivity increases significantly from 0.14 W∙m-1∙K-1 for the pure polymer-derived ceramic (PDC) matrix to 0.30 W∙m-1∙K-1 for a sample containing 55 vol.% PZT filler. From X-ray diffraction experiments (XRD), specific interactions between the filler and matrix are observed; the crystallization of the PDC matrix in the presence of the PZT filler is inhibited; conversely, the PDC matrix results in a pronounced decomposition of the filler compared to the pure PZT material.

| S-EPMC7177491 | biostudies-literature

High Discharge Energy Density at Low Electric Field Using an Aligned Titanium Dioxide/Lead Zirconate Titanate Nanowire Array.

Project description:Polymer-based capacitors with high energy density have attracted significant attention in recent years due to their wide range of potential applications in electronic devices. However, the obtained high energy density is predominantly dependent on high applied electric field, e.g., 400-600 kV mm-1, which may bring more challenges relating to the failure probability. Here, a simple two-step method for synthesizing titanium dioxide/lead zirconate titanate nanowire arrays is exploited and a demonstration of their ability to achieve high discharge energy density capacitors for low operating voltage applications is provided. A high discharge energy density of 6.9 J cm-3 is achieved at low electric fields, i.e., 143 kV mm-1, which is attributed to the high relative permittivity of 218.9 at 1 kHz and high polarization of 23.35 µC cm-2 at this electric field. The discharge energy density obtained in this work is the highest known for a ceramic/polymer nanocomposite at such a low electric field. The novel nanowire arrays used in this work are applicable to a wide range of fields, such as energy harvesting, energy storage, and photocatalysis.

| S-EPMC5827564 | biostudies-literature

Characterization and Design Improvement of a Thickness-Shear Lead Zirconate Titanate Transducer for Low Frequency Ultrasonic Guided Wave Applications.

Project description:Thickness-shear transducers for guided wave testing have been used in industry for over two decades and much research has been conducted to improve the resolution and sensitivity. Due to a geometric feature of the current state-of-the art transducer, there is an out-of-plane component in the propagation direction of the fundamental shear horizontal mode which complicates the signal interpretation. In such case, complex signal processing techniques need to be used for mode discrimination to assess the structural health with higher precision. Therefore, it is important to revise the transducer design to eliminate the out-of-plane components in the propagation direction of fundamental shear horizontal mode. This will enhance the mode purity of fundamental shear horizontal mode for its application in guided wave inspection. A numerical investigation has been conducted on a 3 mm thick 2 m circular steel plate to understand the behaviour and the characteristics of the state-of-the-art thickness-shear transducer. Based on the results, it is noted that the redesigning the electrode arrangement will suppress the out-of-plane components on the propagation direction of the fundamental shear horizontal mode. With the aid of this information current state-of-the-art transducers were redesigned and tested in laboratory conditions using the 3D Laser Doppler Vibrometer. This information will aid future transducer designers improve the resolution of thickness-shear transducers for guided wave applications and reduce the weight and cost of transducer array by eliminating the need of additional transducers to suppress spurious modes.

| S-EPMC6515301 | biostudies-literature

A small-molecule organic ferroelectric with piezoelectric voltage coefficient larger than that of lead zirconate titanate and polyvinylidene difluoride.

Project description:Piezoelectric materials that generate electricity when deforming are ideal for many implantable medical sensing devices. In modern piezoelectric materials, inorganic ceramics and polymers are two important branches, represented by lead zirconate titanate (PZT) and polyvinylidene difluoride (PVDF). However, PVDF is a nondegradable plastic with poor crystallinity and a large coercive field, and PZT suffers from high sintering temperature and toxic heavy element. Here, we successfully design a metal-free small-molecule ferroelectric, 3,3-difluorocyclobutanammonium hydrochloride ((3,3-DFCBA)Cl), which has high piezoelectric voltage coefficients g 33 (437.2 × 10-3 V m N-1) and g 31 (586.2 × 10-3 V m N-1), a large electrostriction coefficient Q 33 (about 4.29 m4 C-2) and low acoustic impedance z 0 (2.25 × 106 kg s-1 m-2), significantly outperforming PZT (g 33 = 34 × 10-3 V m N-1 and z 0 = 2.54 × 107 kg s-1 m-2) and PVDF (g 33 = 286.7 × 10-3 V m N-1, g 31 = 185.9 × 10-3 V m N-1, Q 33 = 1.3 m4 C-2, and z 0 = 3.69 × 106 kg s-1 m-2). Such a low acoustic impedance matches that of the body (1.38-1.99 × 106 kg s-1 m-2) reasonably well, making it attractive as next-generation biocompatible piezoelectric devices for health monitoring and "disposable" invasive medical ultrasound imaging.

| S-EPMC9067616 | biostudies-literature

The Effect of Acceptor and Donor Doping on Oxygen Vacancy Concentrations in Lead Zirconate Titanate (PZT).

Project description:The different properties of acceptor-doped (hard) and donor-doped (soft) lead zirconate titanate (PZT) ceramics are often attributed to different amounts of oxygen vacancies introduced by the dopant. Acceptor doping is believed to cause high oxygen vacancy concentrations, while donors are expected to strongly suppress their amount. In this study, La3+ donor-doped, Fe3+ acceptor-doped and La3+/Fe3+-co-doped PZT samples were investigated by oxygen tracer exchange and electrochemical impedance spectroscopy in order to analyse the effect of doping on oxygen vacancy concentrations. Relative changes in the tracer diffusion coefficients for different doping and quantitative relations between defect concentrations allowed estimates of oxygen vacancy concentrations. Donor doping does not completely suppress the formation of oxygen vacancies; rather, it concentrates them in the grain boundary region. Acceptor doping enhances the amount of oxygen vacancies but estimates suggest that bulk concentrations are still in the ppm range, even for 1% acceptor doping. Trapped holes might thus considerably contribute to the charge balancing of the acceptor dopants. This could also be of relevance in understanding the properties of hard and soft PZT.

| S-EPMC5457210 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data