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Nickel-Aluminum Oxide Aerogels: Super-adsorbents for Azo Dyes for Water Remediation.

ABSTRACT: Highly porous nickel-aluminum oxide aerogels were prepared according to a one-pot sol-gel process and dried under supercritical carbon dioxide conditions. Although the surface properties of these materials were very appealing for applications in catalysis, these aerogels were never applied in adsorption. The nickel effect on the structure and surface properties of the aerogels has been investigated via a broad range of structural, textural, and morphology characterization of the aerogels before and after heat treatment. The adsorption capacity of the as-synthesized and calcined aerogels for azo dyes was assessed under various experimental conditions. The presence of nickel in the aerogel boosts tremendously the surface reactivity and improves noticeably the adsorption capacity of the material. The adsorption capacities for the nickel-aluminum oxide aerogel with 40% nickel (q max) are 900 mg g-1 for methyl orange, 1484 mg g-1 for orange II, and 1660 mg g-1 for Congo Red. The adsorption process is exothermic and follows pseudo-second-order kinetics.

SUBMITTER: Chaaban M

PROVIDER: S-EPMC7594139 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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Nickel-Aluminum Oxide Aerogels: Super-adsorbents for Azo Dyes for Water Remediation.

Chaaban Maya M El-Rassy Houssam H

ACS omega 20201016 42

Highly porous nickel-aluminum oxide aerogels were prepared according to a one-pot sol-gel process and dried under supercritical carbon dioxide conditions. Although the surface properties of these materials were very appealing for applications in catalysis, these aerogels were never applied in adsorption. The nickel effect on the structure and surface properties of the aerogels has been investigated via a broad range of structural, textural, and morphology characterization of the aerogels before ...[more]

PMID: 33134703

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Project description:BackgroundAzo dyes are recalcitrant organic pollutants present in textile industry effluents. Conventional treatment methods to remove them come with a range of disadvantages. Nanoparticles and their nanocomposites offer more efficient, less expensive and easy to handle wastewater treatment alternative.MethodsIn this study, nanoparticles of nickel oxide (NiO-NPs), copper oxide (CuO-NPs) and their nanocomposite (NiO/CuO-NC) were synthesized using co-precipitation method. The functional groups present on the surface of synthesized nanomaterials were verified using Fourier-transform infrared spectroscopy (FTIR). Surface morphology was assessed using scanning electron microscopy (SEM) whereas purity, shape and size of the crystallite were determined using X-ray diffraction (XRD) technique. The potential of these nanomaterials to degrade three dyes i.e., Reactive Red-2 (RR-2), Reactive Black-5 (RB-5) and Orange II sodium salt (OII) azo dyes, was determined in an aqueous medium under visible light (photocatalysis). The photodegradation effectiveness of all nanomaterials was evaluated under different factors like nanomaterial dose (0.02-0.1 g 10 mL-1), concentration of dyes (20-100 mg L-1), and irradiation time (60-120 min). They were also assessed for their potential to adsorb RR-2 and OII dyes.ResultsResults revealed that at optimum concentration (60 mgL-1) of RR-2, RB-5, and OII dyes, NiO-NPs degraded 90, 82 and 83%, CuO-NPs degraded 49, 34, and 44%, whereas the nanocomposite NiO/CuO-NC degraded 92, 93, and 96% of the said dyes respectively. The nanomaterials were categorized as the efficient degraders of the dyes in the order: NiO/CuO-NC > NiO-NPs > CuO-NPs. The highest degradation potential shown by the nanocomposite was attributed to its large surface area, small particles size, and quick reactions which were proved by advance analytical techniques. The equilibrium and kinetic adsorption of RR-2 and OII on NiO-NPs, CuO-NPs, and NiO/CuO-NC were well explained with Langmuir and Pseudo second order model, respectively (R2 ≥ 0.96). The maximum RR-2 adsorption (103 mg/g) was obtained with NiO/CuO-NC. It is concluded that nanocomposites are more efficient and promising for the dyes degradation from industrial wastewater as compared with dyes adsorption onto individual NPs. Thus, the nanocomposite NiO/CuO-NC can be an excellent candidate for photodegradation as well as the adsorption of the dyes in aqueous media.

Dataset Information

Nickel-Aluminum Oxide Aerogels: Super-adsorbents for Azo Dyes for Water Remediation.

Publications

Nickel-Aluminum Oxide Aerogels: Super-adsorbents for Azo Dyes for Water Remediation.

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