Not Completely Innocent: How Argon Binding Perturbs Cationic Copper Clusters.
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ABSTRACT:
SUBMITTER: Jamshidi Z
PROVIDER: S-EPMC7604873 | biostudies-literature | 2020 Oct
REPOSITORIES: biostudies-literature
Publications
Not Completely Innocent: How Argon Binding Perturbs Cationic Copper Clusters.
Jamshidi Zahra Z Lushchikova Olga V OV Bakker Joost M JM Visscher Lucas L
The journal of physical chemistry. A 20201015 43
Argon is often considered as an innocent probe that can be attached and detached to study the structure of a particular species without perturbing the species too much. We have investigated whether this assumption also holds for small copper cationic clusters and demonstrated that small but significant charge transfer from argon to metal changes the remaining binding positions, leading in general, to weaker binding of other argon atoms. The exception is binding to just one copper ion, where the ...[more]
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