Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding.
Ontology highlight
ABSTRACT: Distance dependence of appended Lewis acids in N2H4 binding and deprotonation was evaluated within a series of zinc complexes. Variation of spacer-length to a tethered trialkylborane Lewis acid revealed distinct preferences for binding and stabilization of the resulting deprotonated N2H3- unit.
SUBMITTER: Kiernicki JJ
PROVIDER: S-EPMC7606458 | biostudies-literature |
REPOSITORIES: biostudies-literature
ACCESS DATA