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Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding.


ABSTRACT: Distance dependence of appended Lewis acids in N2H4 binding and deprotonation was evaluated within a series of zinc complexes. Variation of spacer-length to a tethered trialkylborane Lewis acid revealed distinct preferences for binding and stabilization of the resulting deprotonated N2H3- unit.

SUBMITTER: Kiernicki JJ 

PROVIDER: S-EPMC7606458 | biostudies-literature |

REPOSITORIES: biostudies-literature

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