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Absorption cross section of gold nanoparticles based on NIR laser heating and thermodynamic calculations.

ABSTRACT: We present a method for measuring the optical absorption cross section ([Formula: see text]) of gold nanoparticles (GNPs) based on optically heating the solution of GNPs with an 808 nm near-infrared (NIR) laser and measuring the temperature increase of the solution. We rely on the theoretical calculations based on the heat diffusion equations and experimental measurements based on the energy balance equations to measure the [Formula: see text] and the temperature distribution of single GNPs. Several morphologies, including gold nanospheres (GNSs), spherical gold nanoparticle conjugate (AuNPC), which are 20 nm GNSs surface-functionalized with an IR 808 dye, gold nanorods (GNRs), and gold nanourchins (GNUs), were studied. The study found that a single 20 nm GNS has the lowest [Formula: see text] and temperature distribution as compared to 100 nm GNUs. By increasing the size of GNSs from 20 to 30 nm, the magnitude of [Formula: see text] as well as temperature distribution increases by a factor of 5. The [Formula: see text] values of 20 and 30 nm GNSs calculated by Mie theory and the experimentally measured are in a good agreement. GNRs with equivalent radius ([Formula: see text]) 9.16 nm show the second lowest [Formula: see text]. By increasing the [Formula: see text] by a factor of 2 to 19.2 nm, the measured [Formula: see text] and temperature distribution also increased by a factor of 2. We also estimated [Formula: see text] for GNUs with diameters at 80 and 100 nm, which also have higher [Formula: see text] values. This work confirms that we can use temperature to accurately measure the [Formula: see text] of a variety of GNPs in solution.

SUBMITTER: Alrahili M

PROVIDER: S-EPMC7606525 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature

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Absorption cross section of gold nanoparticles based on NIR laser heating and thermodynamic calculations.

Alrahili Mazen M Savchuk Viktoriia V McNear Kelly K Pinchuk Anatoliy A

Scientific reports 20201102 1

We present a method for measuring the optical absorption cross section ([Formula: see text]) of gold nanoparticles (GNPs) based on optically heating the solution of GNPs with an 808 nm near-infrared (NIR) laser and measuring the temperature increase of the solution. We rely on the theoretical calculations based on the heat diffusion equations and experimental measurements based on the energy balance equations to measure the [Formula: see text] and the temperature distribution of single GNPs. Sev ...[more]

PMID: 33139828

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Project description:Optical absorption is the most fundamental optical property characterizing light-matter interactions in materials and can be most readily compared with theoretical predictions. However, determination of optical absorption cross-section of individual nanostructures is experimentally challenging due to the small extinction signal using conventional transmission measurements. Recently, dramatic increase of optical contrast from individual carbon nanotubes has been successfully achieved with a polarization-based homodyne microscope, where the scattered light wave from the nanostructure interferes with the optimized reference signal (the reflected/transmitted light). Here we demonstrate high-sensitivity absorption spectroscopy for individual single-walled carbon nanotubes by combining the polarization-based homodyne technique with broadband supercontinuum excitation in transmission configuration. To our knowledge, this is the first time that high-throughput and quantitative determination of nanotube absorption cross-section over broad spectral range at the single-tube level was performed for more than 50 individual chirality-defined single-walled nanotubes. Our data reveal chirality-dependent behaviors of exciton resonances in carbon nanotubes, where the exciton oscillator strength exhibits a universal scaling law with the nanotube diameter and the transition order. The exciton linewidth (characterizing the exciton lifetime) varies strongly in different nanotubes, and on average it increases linearly with the transition energy. In addition, we establish an empirical formula by extrapolating our data to predict the absorption cross-section spectrum for any given nanotube. The quantitative information of absorption cross-section in a broad spectral range and all nanotube species not only provides new insight into the unique photophysics in one-dimensional carbon nanotubes, but also enables absolute determination of optical quantum efficiencies in important photoluminescence and photovoltaic processes.

Dataset Information

Absorption cross section of gold nanoparticles based on NIR laser heating and thermodynamic calculations.

Publications

Absorption cross section of gold nanoparticles based on NIR laser heating and thermodynamic calculations.

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