Ontology highlight
ABSTRACT:
SUBMITTER: Zatsikha YV
PROVIDER: S-EPMC7658947 | biostudies-literature | 2020 Nov
REPOSITORIES: biostudies-literature
Zatsikha Yuriy V YV Shamova Liliya I LI Schaffner Jacob W JW Healy Andrew T AT Blesener Tanner S TS Cohen Gabriel G Wozniak Brandon B Blank David A DA Nemykin Victor N VN
ACS omega 20201027 44
The electronic communication between two ferrocene groups in the electron-deficient expanded aza-BODIPY analogue of zinc manitoba-dipyrromethene (MB-DIPY) was probed by spectroscopic, electrochemical, spectroelectrochemical, and theoretical methods. The excited-state dynamics involved sub-ps formation of the charge-separated state in the organometallic zinc MB-DIPYs, followed by recovery of the ground state via charge recombination in 12 ps. The excited-state behavior was contrasted with that ob ...[more]