NMR and EPR Study of Homolysis of Diastereomeric Alkoxyamines.
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ABSTRACT:
SUBMITTER: Cherkasov S
PROVIDER: S-EPMC7663419 | biostudies-literature | 2020 Nov
REPOSITORIES: biostudies-literature
Publications
NMR and EPR Study of Homolysis of Diastereomeric Alkoxyamines.
Cherkasov Sergey S Parkhomenko Dmitriy D Genaev Alexander A Salnikov Georgii G Edeleva Mariya M Morozov Denis D Rybalova Tatyana T Kirilyuk Igor I Marque Sylvain R A SRA Bagryanskaya Elena E
Molecules (Basel, Switzerland) 20201101 21
Three alkoxyamines based on imidazoline radicals with a pyridine functional group-potential initiators of nitroxide-mediated, controlled radical polymerization-were synthesized. Electron Paramagnetic Resonance (EPR) measurements reveal biexponential kinetics for the thermolysis for diastereomeric alkoxyamines and monoexponential kinetics for an achiral alkoxyamine. For comparison, the thermolysis of all three alkoxyamines was studied by NMR in the presence of three different scavengers, namely t ...[more]
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