Ontology highlight
ABSTRACT:
SUBMITTER: Alkorta I
PROVIDER: S-EPMC7663457 | biostudies-literature | 2020 Oct
REPOSITORIES: biostudies-literature
Alkorta Ibon I Elguero José J Trujillo Cristina C Sánchez-Sanz Goar G
International journal of molecular sciences 20201028 21
The geometry, energy and electron density properties of the 1:1, 1:2 and 1:3 complexes between cyclic (Py-M)<sub>3</sub> (M = Au, Ag and Cu) and halide ions (F<sup>-</sup>, Cl<sup>-</sup> and Br<sup>-</sup>) were studied using Møller Plesset (MP2) computational methods. Three different configurations were explored. In two of them, the anions interact with the metal atoms in planar and apical dispositions, while in the last configuration, the anions interact with the CH(4) group of the pyrazole. ...[more]