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The niobium and tantalum concentration in the mantle constrains the composition of Earth's primordial magma ocean.

ABSTRACT: The bulk silicate Earth (BSE), and all its sampleable reservoirs, have a subchondritic niobium-to-tantalum ratio (Nb/Ta). Because both elements are refractory, and Nb/Ta is fairly constant across chondrite groups, this can only be explained by a preferential sequestration of Nb relative to Ta in a hidden (unsampled) reservoir. Experiments have shown that Nb becomes more siderophile than Ta under very reducing conditions, leading the way for the accepted hypothesis that Earth's core could have stripped sufficient amounts of Nb during its formation to account for the subchondritic signature of the BSE. Consequently, this suggestion has been used as an argument that Earth accreted and differentiated, for most of its history, under very reducing conditions. Here, we present a series of metal-silicate partitioning experiments of Nb and Ta in a laser-heated diamond anvil cell, at pressure and temperature conditions directly comparable to those of core formation; we find that Nb is more siderophile than Ta under any conditions relevant to a deep magma ocean, confirming that BSE's missing Nb is in the core. However, multistage core formation modeling only allows for moderately reducing or oxidizing accretionary conditions, ruling out the need for very reducing conditions, which lead to an overdepletion of Nb from the mantle (and a low Nb/Ta ratio) that is incompatible with geochemical observations. Earth's primordial magma ocean cannot have contained less than 2% or more than 18% FeO since the onset of core formation.

SUBMITTER: Huang D

PROVIDER: S-EPMC7668002 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:Recent analytical advances have provided means to measure potassium (K) isotopes in various terrestrial materials, but little is known about K distribution and stable isotope composition in the lithospheric mantle because of: (a) common low K abundances, (b) potential contamination and alteration, (c) diversity of mantle rocks and minerals hosting K in different tectonic settings. We report K abundances and δ41K values for well-studied whole-rock (WR) mantle xenoliths (spinel and garnet peridotites and pyroxenites) from mobile belts, a craton, a subduction zone, as well as for K-rich phases (mica, amphibole, silicate glass) and xenolith-bearing volcanic materials (67 samples). The xenolith materials show extremely broad ranges of K content (7 μg/g to 6.6 wt.%) and δ41K (-2.77‰ to 0.62‰). They contrast with the narrow δ41K range for host volcanic materials (-0.53‰ to -0.27‰) and literature data on oceanic basalts (melting products of upwelling asthenosphere: -0.43 ± 0.17‰, 2sd). Amphibole-bearing subduction zone peridotites show the highest WR δ41K values (0.40 to 0.62‰) likely inherited from fluids released into the mantle wedge from subducted oceanic crust. All other WR samples yield negative δ41K: -0.06‰ to -2.77‰ for peridotites and -0.17‰ to -0.52‰ for pyroxenites. The δ41K in K-rich mantle phases range from positive values (0.16 to 0.57‰) for phlogopite in strongly metasomatized peridotites to negative values (-0.27 to -0.94‰) for phlogopite, amphibole and glass pockets from other samples, which cannot be explained by equilibrium inter-mineral fractionation inferred from ab initio calculations. We attribute the broad δ41K variations to (a) isotope fractionation during fluid-rock interaction in the mantle, and (b) distinct sources of K-bearing fluids. Kinetic isotope fractionation during fluid percolation and diffusion is inferred for composite xenoliths (phlogopite and pyroxenite veins in peridotites) that have lower δ41K in the hosts than in the veins due to slower migration of 41K than 39K from the veins (former fluid channels) to host mantle. Overall, the K isotope fractionation in the lithospheric mantle appears to be greater than for magmatic fractionation in the crust. The average δ41K of normal off-craton continental lithospheric mantle calculated from the least altered fertile and lightly metasomatized lherzolites is -0.57 ± 0.28‰ (2sd). This value is within error (though a little lower) of estimates for both continental crust and MORB and OIB mantle sources indicating that these major silicate Earth reservoirs have similar bulk δ41K values, apparently due to low or negligible K isotopic fractionation during their formation by magmatic differentiation and melting. By contrast, K isotopes in modern and fossil subduction zones are fractionated via fluid-related equilibrium and kinetic processes.

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The niobium and tantalum concentration in the mantle constrains the composition of Earth's primordial magma ocean.

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