Chemistry of Tetradentate [C,N?:?C,N] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations.
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ABSTRACT:
SUBMITTER: Munin-Cruz P
PROVIDER: S-EPMC7670630 | biostudies-literature | 2020 Nov
REPOSITORIES: biostudies-literature
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Chemistry of Tetradentate [<i>C</i>,<i>N : C</i>,<i>N</i>] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations.
Munín-Cruz Paula P Reigosa Francisco F Rúa-Sueiro Marcos M Ortigueira Juan M JM Pereira M Teresa MT Vila José M JM
ChemistryOpen 20201117 11
A theoretical and experimental study of tetradentate [C,N : C,N] iminophosphorane palladacycles was carried out for the purpose of elucidating their behavior as compared to the parent Schiff base analogues to determine the prospect of encountering new A-frame structures for the iminophosphorane derivatives. The DFT calculations were in agreement with the experimental results regarding the performance of these ligands. New insights into the chemistry of the related dinuclear species have been obt ...[more]
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