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Photodynamic Pattern Memory Surfaces with Responsive Wrinkled and Fluorescent Patterns.

ABSTRACT: Reversible pattern systems, namely pattern memory surfaces, possessing tunable morphology play an important role in the development of smart materials; however, the construction of these surfaces is still extensively challenging because of complicated methodologies or chemical reactions. Herein, a functionalized basement is strategically integrated with a multi-responsive supramolecular network based on hydrogen bonding between aggregation-induced emission luminogens (AIEgens) and copolymers containing amidogen (poly(St-co-Dm) to establish a bilayer system for near-infrared (NIR)-driven memory dual-pattern, where both the fluorescence emission and wrinkled structures can be concurrently regulated by a noninvasive NIR input. The motion of the AIEgens and photo-to-thermal expansion of the modified base allow temporal erasing of the fluorescent wrinkling patterns. Meanwhile, when exposed to 365 nm UV radiation, the fluorescent patterns can be independently regulated through photocyclization. The fluorescent wrinkling pattern presented herein is successfully demonstrated to promote the level of information security and capacity. This strategy provides a brand-new approach for the development of smart memory interfaces.

SUBMITTER: Chen S

PROVIDER: S-EPMC7675060 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature

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Photodynamic Pattern Memory Surfaces with Responsive Wrinkled and Fluorescent Patterns.

Chen Shuai S Ma Tianjiao T Bai Jing J Ma Xiaodong X Yin Jie J Jiang Xuesong X

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20201014 22

Reversible pattern systems, namely pattern memory surfaces, possessing tunable morphology play an important role in the development of smart materials; however, the construction of these surfaces is still extensively challenging because of complicated methodologies or chemical reactions. Herein, a functionalized basement is strategically integrated with a multi-responsive supramolecular network based on hydrogen bonding between aggregation-induced emission luminogens (AIEgens) and copolymers con ...[more]

PMID: 33240777

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Project description:The generation of microstructured patterns on the surface of a specific polymeric material could radically improve their performance in a particular application. Most of the interactions with the environment occur at the material interface; therefore, increasing the exposed active surface considerably improves their range of application. In this article, a simple and reliable protocol to form spontaneous wrinkled patterns using a hydrogel layer is reported. For this purpose, we took advantage of the doctor blade technique in order to generate homogenous films over solid substrates with controlled thickness and large coverage. The hydrogel wrinkle formation involves a prepolymerization step which produces oligomers leading to a solution with increased viscosity, enough for doctor blade deposition. Subsequently, the material was exposed to vacuum and plasma to trigger wrinkled pattern formation. Finally, a UV-polymerization treatment was applied to fix the undulations on top. Interestingly, the experimental parameters allowed us to finely tune the wrinkle characteristics (period, amplitude, and orientation). For this study, two main aspects were explored. The first one is related to the role of the substrate functionalization on the wrinkle formation. The second study correlates the deswelling time and its relationship with the dimensions and distribution of the wrinkle pattern. In the first batch, four different 3-(trimethoxysilyl)propyl methacrylate (TSM) concentrations were used to functionalize the substrate in order to enhance the adhesion between hydrogel film and the substrate. The wrinkles formed were characterized in terms of wrinkle amplitude, wavelength, pattern roughness, and surface Young modulus, by using AFM in imaging and force spectroscopy modes. Moreover, the chemical composition of the hydrogel film cross-section and the effect of the plasma treatment were analyzed with confocal Raman spectroscopy. These results demonstrated that an oxidized layer was formed on top of the hydrogel films due to the exposure to an argon plasma.

Dataset Information

Photodynamic Pattern Memory Surfaces with Responsive Wrinkled and Fluorescent Patterns.

Publications

Photodynamic Pattern Memory Surfaces with Responsive Wrinkled and Fluorescent Patterns.

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