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Dinuclear Gold(I) Complexes Bearing N,N'-Allyl-Bridged Bisimidazolylidene Ligands.

ABSTRACT: A novel N,N'-allyl-bridged bisimidazolium salt and a novel dinuclear Ag(I) and a Au(I) NHC complex are reported. Both metallacyclic complexes have a twisted structural shape due to the rigid allylic system and form two different isomers relating to the position of the double bonds. The allyl-group shows photoisomerisation, but no reactivity towards bases for the additional coordination of Pd(II).

SUBMITTER: Jakob CHG 

PROVIDER: S-EPMC7687270 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature

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Dinuclear Gold(I) Complexes Bearing N,N'-Allyl-Bridged Bisimidazolylidene Ligands.

Jakob Christian H G CHG   Dominelli Bruno B   Rieb Julia J   Jandl Christian C   Pöthig Alexander A   Reich Robert M RM   Correia João D G JDG   Kühn Fritz E FE  

Chemistry, an Asian journal 20200528 12

A novel N,N'-allyl-bridged bisimidazolium salt and a novel dinuclear Ag(I) and a Au(I) NHC complex are reported. Both metallacyclic complexes have a twisted structural shape due to the rigid allylic system and form two different isomers relating to the position of the double bonds. The allyl-group shows photoisomerisation, but no reactivity towards bases for the additional coordination of Pd(II). ...[more]

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