Ontology highlight
ABSTRACT:
SUBMITTER: Jakob CHG
PROVIDER: S-EPMC7687270 | biostudies-literature | 2020 Jun
REPOSITORIES: biostudies-literature
Chemistry, an Asian journal 20200528 12
A novel N,N'-allyl-bridged bisimidazolium salt and a novel dinuclear Ag(I) and a Au(I) NHC complex are reported. Both metallacyclic complexes have a twisted structural shape due to the rigid allylic system and form two different isomers relating to the position of the double bonds. The allyl-group shows photoisomerisation, but no reactivity towards bases for the additional coordination of Pd(II). ...[more]