Unknown

Dataset Information

0

Regioselective Functionalization of the Mesoporous Metal-Organic Framework, NU-1000, with Photo-Active Tris-(2,2'-bipyridine)ruthenium(II).

ABSTRACT: Solvent-assisted ligand incorporation is an excellent method for the post-synthetic functionalization of Zr-based metal-organic frameworks (MOFs), as carboxylate-derivative functionalities readily coordinate to the Zr6 nodes by displacing node-based aqua and terminal hydroxo ligands. In this study, a photocatalytically active ruthenium complex RuII(bpy)2(dcbpy), that is, bis-(2,2'-bipyridine)-(4,4'-dicarboxy-2,2'-bipyridine)ruthenium, was installed in the mono-protonated (carboxylic acid) form within NU-1000 via SALI. Crystallographic information regarding the siting of the ruthenium complex within the MOF pores is obtained by difference envelope density analysis. The ruthenium-functionalized MOF, termed Ru-NU-1000, shows excellent heterogeneous photocatalytic activity for an oxidative amine coupling reaction.

SUBMITTER: Nagatomi H 

PROVIDER: S-EPMC7689908 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Regioselective Functionalization of the Mesoporous Metal-Organic Framework, NU-1000, with Photo-Active Tris-(2,2'-bipyridine)ruthenium(II).

Nagatomi Hisanori H   Gallington Leighanne C LC   Goswami Subhadip S   Duan Jiaxin J   Chapman Karena W KW   Yanai Nobuhiro N   Kimizuka Nobuo N   Farha Omar K OK   Hupp Joseph T JT  

ACS omega 20201109 46

Solvent-assisted ligand incorporation is an excellent method for the post-synthetic functionalization of Zr-based metal-organic frameworks (MOFs), as carboxylate-derivative functionalities readily coordinate to the Zr<sub>6</sub> nodes by displacing node-based aqua and terminal hydroxo ligands. In this study, a photocatalytically active ruthenium complex Ru<sup>II</sup>(bpy)<sub>2</sub>(dcbpy), that is, bis-(2,2'-bipyridine)-(4,4'-dicarboxy-2,2'-bipyridine)ruthenium, was installed in the mono-pr  ...[more]

Similar Datasets

Unknown Poly[diaqua-bis(2,2'-bipyridine)tris-(?(4)-2,2'-bipyridine-4,4'-dicarboxyl-ato)dineodymium(III)].
| S-EPMC2915173 | biostudies-literature
Unknown Tris(2,2'-bipyridine-κN:N')cobalt(III) trichloride tetra-hydrate.
| S-EPMC2959986 | biostudies-literature
Unknown Protein destabilisation by ruthenium(II) tris-bipyridine based protein-surface mimetics.
| S-EPMC3731202 | biostudies-literature
Unknown Tris(2,2'-bipyridine)-nickel(II) hexa-molybdate.
| S-EPMC3007854 | biostudies-other
Unknown Tris(2,2'-bipyridine-?N,N')cobalt(III) tris-(oxalato-?O,O)ferrate(III) mono-hydrate.
| S-EPMC3297208 | biostudies-literature
Unknown Tris(2,2'-bipyridine-?N,N')cobalt(III) octa-cyanido-tungstate(V).
| S-EPMC2980176 | biostudies-literature
Unknown Tris(2,2'-bipyridine-?(2) N,N')cobalt(II) bis-(hexa-fluoridophosphate).
| S-EPMC3588389 | biostudies-literature
Unknown Bis(2,2'-bipyridine-?(2)N,N')tris-(nitrato-?(2)O,O')erbium(III).
| S-EPMC3344325 | biostudies-literature
Unknown Tris(2,2'-bipyridine)-copper(II) penta-cyanido-nitro-soferrate(II) methanol disolvate monohydrate.
| S-EPMC3629489 | biostudies-literature
Unknown cis-Bis(acetonitrile-?N)bis-(2,2'-bipyridine-?N,N')ruthenium(II) tetra-fluoridoborate.
| S-EPMC3254331 | biostudies-literature