Ontology highlight
ABSTRACT:
SUBMITTER: Fu D
PROVIDER: S-EPMC7692936 | biostudies-literature | 2020 Nov
REPOSITORIES: biostudies-literature
Fu Donglong D Lucini Paioni Alessandra A Lian Cheng C van der Heijden Onno O Baldus Marc M Weckhuysen Bert M BM
Angewandte Chemie (International ed. in English) 20200911 45
The chemical industry has exploited zeolite shape selectivity for more than 50 years, yet our fundamental understanding remains incomplete. Herein, the zeolite channel geometry-reactive intermediate relationships are studied in detail using anisotropic zeolite ZSM-5 crystals for the methanol-to-hydrocarbon (MTH) process, and advanced magic-angle spinning solid-state NMR (ssNMR) spectroscopy. The utilization of anisotropic ZSM-5 crystals enabled the preferential formation of reaction intermediate ...[more]