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Phosphorus-Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry.

ABSTRACT: A concise synthetic route towards a new family of phosphorus-containing polycyclic aromatic hydrocarbons starting from the versatile acridophosphine has been established. The structural and optoelectronic properties of these compounds were efficiently modulated through derivatization of the phosphorus center. X-ray crystallographic analysis, UV/Vis spectroscopic, and electrochemical studies supported by DFT calculations identified the considerable potential of these scaffolds for the development of organophosphorus functional materials with tailored properties upon further functionalization.

SUBMITTER: Ascherl JDR 

PROVIDER: S-EPMC7693108 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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Phosphorus-Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry.

Ascherl Johannes D R JDR   Neiß Christian C   Vogel Alexander A   Graf Jürgen J   Rominger Frank F   Oeser Thomas T   Hampel Frank F   Görling Andreas A   Kivala Milan M  

Chemistry (Weinheim an der Bergstrasse, Germany) 20200917 58

A concise synthetic route towards a new family of phosphorus-containing polycyclic aromatic hydrocarbons starting from the versatile acridophosphine has been established. The structural and optoelectronic properties of these compounds were efficiently modulated through derivatization of the phosphorus center. X-ray crystallographic analysis, UV/Vis spectroscopic, and electrochemical studies supported by DFT calculations identified the considerable potential of these scaffolds for the development  ...[more]

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