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ABSTRACT:
SUBMITTER: Bera MK
PROVIDER: S-EPMC7698060 | biostudies-literature | 2020 Nov
REPOSITORIES: biostudies-literature
Bera Manas Kumar MK Ninomiya Yoshikazu Y Higuchi Masayoshi M
Molecules (Basel, Switzerland) 20201111 22
A heterobimetallic supramolecular polymer (polyRuFe) with alternately complexed Ru(II) and Fe(II) is prepared following a stepwise synthetic route through harnessing first the strongly binding metal ion Ru(II) and then the weakly binding metal ion Fe(II). A high yield of product is achieved in each step. The heterometal ions are incorporated into the polymer chain in identical coordination environments formed by two 2,2':6',2″-terpyridine moieties. Characterization is accomplished by NMR spectro ...[more]