Electric and Photocatalytic Properties of Graphene Oxide Depending on the Degree of Its Reduction.

ABSTRACT: When graphene oxide is reduced, the functional groups are released and the structure becomes more ordered. The degree of reduction might be tunable with the process parameters. In our work, graphene oxide is prepared and the effect of thermal and chemical reduction is investigated. The samples are characterized with TG/DTA-MS, SEM-EDX, TEM, XPS, ATR-FTIR, Raman spectroscopy and XRD. Their electrical resistance, cyclic voltammetry and photocatalytic activity data are investigated. The conductivity can be varied by several orders of magnitude, offering a tool to match its electrical properties to certain applications. Low temperature reduction in air offers a material with the highest capacitance, which might be used in supercapacitors. The bare graphene oxide has considerably larger photocatalytic activity than P25 TiO₂. Reduction decreases the activity, meaning that reduced graphene oxide can be used as an electron sink in composite photocatalysts, but does not contribute to the photocatalytic activity by itself.

SUBMITTER: Bakos LP 

PROVIDER: S-EPMC7700189 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature