Ontology highlight
ABSTRACT:
SUBMITTER: Amirjalayer S
PROVIDER: S-EPMC7702088 | biostudies-literature | 2020 Nov
REPOSITORIES: biostudies-literature
Amirjalayer Saeed S Bakker Anne A Freitag Matthias M Glorius Frank F Fuchs Harald H
Angewandte Chemie (International ed. in English) 20201004 47
Atomically precise tailoring of interface structures is crucial for developing functional materials. We demonstrate an N-heterocyclic carbene (NHC) based molecular tool, which modifies the structure of a gold surface with atomic accuracy by the formation of gold nanorods. After adsorption on the gold surface, individual surface atoms are pulled out by the NHCs, generating single-atom surface defects and mobile NHC-Au species. Atomistic calculations reveal that these molecular "ballbots" can act ...[more]