Ontology highlight
ABSTRACT:
SUBMITTER: Wilson DWN
PROVIDER: S-EPMC7702093 | biostudies-literature | 2020 Oct
REPOSITORIES: biostudies-literature
Chemistry (Weinheim an der Bergstrasse, Germany) 20201008 59
We describe the reactivity of two linkage isomers of a boryl-phosphaethynolate, [B]OCP and [B]PCO (where [B]=N,N'-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaboryl), towards tris- (pentafluorophenyl)borane (BCF). These reactions afforded three constitutional isomers all of which contain a phosphaalkene core. [B]OCP reacts with BCF through a 1,2 carboboration reaction to afford a novel phosphaalkene, E-[B]O{(C<sub>6</sub> F<sub>5</sub> )<sub>2</sub> B}C=P(C<sub>6</sub> F<sub>5</sub> ), w ...[more]