Asymmetric Synthesis of Oxygenated Monoterpenoids of Importance for Bark Beetle Ecology.
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ABSTRACT:
SUBMITTER: Ganji S
PROVIDER: S-EPMC7705961 | biostudies-literature | 2020 Nov
REPOSITORIES: biostudies-literature
Publications
Asymmetric Synthesis of Oxygenated Monoterpenoids of Importance for Bark Beetle Ecology.
Ganji Suresh S Svensson Fredric G FG Unelius C Rikard CR
Journal of natural products 20201110 11
Herein we report the asymmetric syntheses of a number of oxygenated terpenoids that are of importance in the chemical ecology of bark beetles. These are pinocamphones, isopinocamphones, pinocarvones, and 4-thujanols (= sabinene hydrates). The camphones were synthesized from isopinocampheol, the pinocarvones from β-pinene, and the thujanols from sabinene. The NMR spectroscopic data, specific rotations, and elution orders of their stereoisomers on a chiral GC-phase (β-cyclodextrin) are also report ...[more]
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