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Efficient Deep Blue Platinum Acetylide Phosphors with Acyclic Diaminocarbene Ligands.

ABSTRACT: Here we report five blue-phosphorescent platinum bis-phenylacetylide complexes with an investigation of their photophysical and electrochemical attributes. Three of the complexes (1-3) are of the general formula cis-Pt(CNR)₂ (C≡CPh)₂ , in which CNR is a variably substituted isocyanide and C≡CPh is phenylacetylide. These isocyanide complexes serve as precursors for complexes of the general formula cis-Pt(CNR)(ADC)(C≡CPh)₂ (4 and 5), in which ADC is an acyclic diaminocarbene installed by amine nucleophilic addition to one of the isocyanides. All of the complexes exhibit deep blue phosphorescence with λ_max ∼430 nm in poly(methyl methacrylate) (PMMA) thin films. Whereas isocyanide complexes 1-3 exhibit modest photoluminescence quantum yields (Φ_PL ), incorporation of one acyclic diaminocarbene ligand results in a three-fold to 16-fold increase in Φ_PL while still maintaining an identical deep blue color profile.

SUBMITTER: Wu Y

PROVIDER: S-EPMC7722030 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature

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Efficient Deep Blue Platinum Acetylide Phosphors with Acyclic Diaminocarbene Ligands.

Wu Yanyu Y Wen Zhili Z Wu Judy I-Chia JI Teets Thomas S TS

Chemistry (Weinheim an der Bergstrasse, Germany) 20201022 68

Here we report five blue-phosphorescent platinum bis-phenylacetylide complexes with an investigation of their photophysical and electrochemical attributes. Three of the complexes (1-3) are of the general formula cis-Pt(CNR)2 (C≡CPh)2 , in which CNR is a variably substituted isocyanide and C≡CPh is phenylacetylide. These isocyanide complexes serve as precursors for complexes of the general formula cis-Pt(CNR)(ADC)(C≡CPh)2 (4 and 5), in which ADC is an acyclic diam ...[more]

PMID: 32640058

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