Construction of pillar[4]arene[1]quinone-1,10-dibromodecane pseudorotaxanes in solution and in the solid state.

ABSTRACT: We report novel pseudorotaxanes based on the complexation between pillar[4]arene[1]quinone and 1,10-dibromodecane. The complexation is found to have a 1:1 host-guest complexation stoichiometry in chloroform but a 2:1 host-guest complexation stoichiometry in the solid state. From single crystal X-ray diffraction, the linear guest molecules thread into cyclic pillar[4]arene[1]quinone host molecules in the solid state, stabilized by CH???? interactions and hydrogen bonds. The bromine atoms at the periphery of the guest molecule provide convenience for the further capping of the pseudorotaxanes to construct rotaxanes.

SUBMITTER: Sheng X 

PROVIDER: S-EPMC7722622 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature