Ontology highlight
ABSTRACT:
SUBMITTER: Deng R
PROVIDER: S-EPMC7730060 | biostudies-literature | 2019
REPOSITORIES: biostudies-literature
Deng Ru R Milton Margarita M Pomarico Scott K SK Weck Marcus M
Polymer chemistry 20190827 37
We report the first heterotelechelic helical poly(methacrylamide) (PMAc) bearing orthogonal supramolecular binding sites on its chain-ends synthesized through a combination of reversible addition-fragmentation chain-transfer (RAFT) polymerization and thiol-bromo "click" chemistry. The heterotelechelic PMAc was assembled with two monotelechelic polymers featuring different secondary structures, namely a coil-like poly(styrene) and a helical poly(isocyanide), resulting in the formation of a coil-h ...[more]