Dataset Information

Unravelling the interfacial interaction in mesoporous SiO₂@nickel phyllosilicate/TiO₂ core-shell nanostructures for photocatalytic activity.

ABSTRACT: Core-shell based nanostructures are attractive candidates for photocatalysis owing to their tunable physicochemical properties, their interfacial contact effects, and their efficacy in charge-carrier separation. This study reports, for the first time, on the synthesis of mesoporous silica@nickel phyllosilicate/titania (mSiO₂@NiPS/TiO₂) core-shell nanostructures. The TEM results showed that the mSiO₂@NiPS composite has a core-shell nanostructure with a unique flake-like shell morphology. XPS analysis revealed the successful formation of 1:1 nickel phyllosilicate on the SiO₂ surface. The addition of TiO₂ to the mSiO₂@NiPS yielded the mSiO₂@NiPS/TiO₂ composite. The bandgap energy of mSiO₂@NiPS and of mSiO₂@NiPS/TiO₂ were estimated to be 2.05 and 2.68 eV, respectively, indicating the role of titania in tuning the optoelectronic properties of the SiO₂@nickel phyllosilicate. As a proof of concept, the core-shell nanostructures were used as photocatalysts for the degradation of methyl violet dye and the degradation efficiencies were found to be 72% and 99% for the mSiO₂@NiPS and the mSiO₂@NiPS/TiO₂ nanostructures, respectively. Furthermore, a recyclability test revealed good stability and recyclability of the mSiO₂@NiPS/TiO₂ photocatalyst with a degradation efficacy of 93% after three cycles. The porous flake-like morphology of the nickel phyllosilicate acted as a suitable support for the TiO₂ nanoparticles. Further, a coating of TiO₂ on the mSiO₂@NiPS surface greatly affected the surface features and optoelectronic properties of the core-shell nanostructure and yielded superior photocatalytic properties.

SUBMITTER: Mutuma BK

PROVIDER: S-EPMC7736695 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Unravelling the interfacial interaction in mesoporous SiO2@nickel phyllosilicate/TiO2 core-shell nanostructures for photocatalytic activity.

Mutuma Bridget K BK Mathebula Xiluva X Nongwe Isaac I Mtolo Bonakele P BP Matsoso Boitumelo J BJ Erasmus Rudolph R Tetana Zikhona Z Coville Neil J NJ

Beilstein journal of nanotechnology 20201209

Core-shell based nanostructures are attractive candidates for photocatalysis owing to their tunable physicochemical properties, their interfacial contact effects, and their efficacy in charge-carrier separation. This study reports, for the first time, on the synthesis of mesoporous silica@nickel phyllosilicate/titania (mSiO2@NiPS/TiO2) core-shell nanostructures. The TEM results showed that the mSiO2@NiPS composite has a core-shell nanostructure with a unique flak ...[more]

PMID: 33364142

Similar Datasets

Project description:SiO2@TiO2 core-shell nanoparticles were successfully synthesized via a simple, reproducible, and low-cost method and tested for methylene blue adsorption and UV photodegradation, with a view to their application in wastewater treatment. The monodisperse SiO2 core was obtained by the classical Stöber method and then coated with a thin layer of TiO2, followed by calcination or hydrothermal treatments. The properties of SiO2@TiO2 core-shell NPs resulted from the synergy between the photocatalytic properties of TiO2 and the adsorptive properties of SiO2. The synthesized NPs were characterized using FT-IR spectroscopy, HR-TEM, FE-SEM, and EDS. Zeta potential, specific surface area, and porosity were also determined. The results show that the synthesized SiO2@TiO2 NPs that are hydrothermally treated have similar behaviors and properties regardless of the hydrothermal treatment type and synthesis scale and better performance compared to the SiO2@TiO2 calcined and TiO2 reference samples. The generation of reactive species was determined by EPR, and the photocatalytic activity was evaluated by the methylene blue (MB) removal in aqueous solution under UV light. Hydrothermally treated SiO2@TiO2 showed the highest adsorption capacity and photocatalytic removal of almost 100% of MB after 15 min in UV light, 55 and 89% higher compared to SiO2 and TiO2 reference samples, respectively, while the SiO2@TiO2 calcined sample showed 80%. It was also observed that the SiO2-containing samples showed a considerable adsorption capacity compared to the TiO2 reference sample, which improved the MB removal. These results demonstrate the efficient synergy effect between SiO2 and TiO2, which enhances both the adsorption and photocatalytic properties of the nanomaterial. A possible photocatalytic mechanism was also proposed. Also noteworthy is that the performance of the upscaled HT1 sample was similar to one of the lab-scale synthesized samples, demonstrating the potentiality of this synthesis methodology in producing candidate nanomaterials for the removal of contaminants from wastewater.

Project description:In this article, the TiO2/SiO2-np nanocomposite multilayer films were synthesized in a single step by reactive magnetron sputtering combined with a nanoparticle aerosol jet. The SiO2 nanoparticles (SiO2-np) were introduced into a growing TiO2 thin film with different time sequences during deposition for a fixed duration. The SiO2-np acting as impurities are introduced into the TiO2 to willingly disturb its growth and to cause growth defects in order to increase the specific surface area of the photocatalytic film. In reason of the non-photoactive properties of the SiO2 nanoparticles, their introduction allows us to study only the effects induced on the film morphology, microstructure, and photocatalytic properties by their incorporation. The fractographies and topographies reveal strong changes in the morphologies depending on the time sequence of the nanoparticle introduction in the thin films. The introduction of SiO2-np from the beginning of the TiO2 film growth leads to the formation of high and large growth defects resulting in a highly diffusive surface. In addition, XRD analysis shows that the crystallite size tends to decrease as the composite film layer gets closer to the surface. Their photocatalytic performance is obtained by following the degradation of orange G dye under UV-visible irradiation. The photocatalytic performance is not only related to the specific surface area of the catalyst film, and the coverage of the photoactive phase on the surface, but also to the crystal quality of the photoactive phase. Furthermore, the samples exhibit good photostability, maintaining the same activity after four degradation cycles. In the specific case of TiO2/SiO2-np, it is demonstrated that the introduction of the nanoparticles only at the beginning of the film growth is more efficient than a continuous introduction. This result suggests that this original process allows the use of a relevant strategy for the nanoparticle introduction according to the required functionality.

Project description:Perfluorooctanoic acid (PFOA), a typical perfluorinated carboxylic acid, is an emerging type of permanent organic pollutants that are regulated by the Stockholm Convention. The degradation of PFOA, however, is quite challenging largely due to the ultra-high stability of C-F bonds. Compared with other techniques, photocatalytic degradation offers the potential advantages of simple operation under mild conditions as well as exceptional decomposition and defluorination efficiency. Titanium dioxide (TiO2) is one of the most frequently used photocatalysts, but so far, the pristine nanosized TiO2 (e.g., the commercial P25) has been considered inefficient for PFOA degradation, since the photo-generated hydroxyl radicals from TiO2 are not able to directly attack C-F bonds. Mesoporous Sb2O3/TiO2 heterojunctions were therefore rationally designed in this work, of which the confined Sb2O3 nanoparticles in mesoporous TiO2 framework could not only tune the band structure and also increase the number of active sites for PFOA degradation. It was found that, after loading Sb2O3, the absorption of UV light was enhanced, indicating a higher efficiency of light utilization; while the band gap was reduced, which accelerated the separation of photo-generated charge carriers; and most importantly, the valence band edge of the Sb2O3/TiO2 heterojunction was significantly lifted so as to prevent the occurrence of hydroxyl radical pathway. Under the optimal ratio of Sb2O3-TiO2, the resulting catalysts managed to remove 81.7% PFOA in 2 h, with a degradation kinetics 4.2 times faster than the commercial P25. Scavenger tests and electron spin resonance spectra further revealed that such improvement was mainly attributed to the formation of superoxide radicals and photo-generated holes, in which the former drove the decarboxylation from C7F15COOH-C7F15 •, and the latter promoted the direct electron transfer for the conversion of C7F15COO--C7F15COO•. The Sb2O3/TiO2 photocatalysts were highly recyclable, with nearly 90% of the initial activity being retained after five consecutive cycles, guaranteeing the feasibility of long-term operation.

Dataset Information

Unravelling the interfacial interaction in mesoporous SiO₂@nickel phyllosilicate/TiO₂ core-shell nanostructures for photocatalytic activity.

Publications

Unravelling the interfacial interaction in mesoporous SiO<sub>2</sub>@nickel phyllosilicate/TiO<sub>2</sub> core-shell nanostructures for photocatalytic activity.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets