Browse
Submit Data
Databases
API
Help

Dataset Information

28 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

The Metaphosphite (PO₂ ^- ) Anion as a Ligand.

ABSTRACT: The utilization of monomeric, lower phosphorous oxides and oxoanions, such as metaphosphite (PO₂ ^- ), which is the heavier homologue of the common nitrite anion but previously only observed in the gas phase and by matrix isolation, requires new synthetic strategies. Herein, a series of rhenium(I-III) complexes with PO₂ ^- as ligand is reported. Synthetic access was enabled by selective oxygenation of a terminal phosphide complex. Spectroscopic and computational examination revealed slightly stronger ?-donor and comparable ?-acceptor properties of PO₂ ^- compared to homologous NO₂ ^- , which is one of the archetypal ligands in coordination chemistry.

SUBMITTER: Abbenseth J

PROVIDER: S-EPMC7756739 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

The Metaphosphite (PO2 - ) Anion as a Ligand.

Abbenseth Josh J Wätjen Florian F Finger Markus M Schneider Sven S

Angewandte Chemie (International ed. in English) 20201025 52

The utilization of monomeric, lower phosphorous oxides and oxoanions, such as metaphosphite (PO2 - ), which is the heavier homologue of the common nitrite anion but previously only observed in the gas phase and by matrix isolation, requires new synthetic strategies. Herein, a series of rhenium(I-III) complexes with PO2 - as ligand is reported. Synthetic access was enabled by selective oxygenation of a terminal phosphide complex. Spectroscopic and compu ...[more]

PMID: 32936501

Similar Datasets

Cu3(PO4)2: Novel Anion Convertor for Aqueous Dual-Ion Battery.

Project description: Not available

| S-EPMC8187538 | biostudies-literature

Anion-adaptive crystalline cationic material for 99TcO4- trapping.

Project description:Efficient anion recognition is of great significance for radioactive 99TcO4- decontamination, but it remains a challenge for traditional sorbents. Herein, we put forward a tactic using soft crystalline cationic material with anion-adaptive dynamics for 99TcO4- sequestration. A cucurbit[8]uril-based supramolecular metal-organic material is produced through a multi-component assembly strategy and used as a sorbent for effective trapping of TcO4-. Excellent separation of TcO4-/ReO4- is demonstrated by fast removal kinetics, good sorption capacity and high distribution coefficient. Remarkably, the most superior selectivity among metal-organic materials reported so far, together with good hydrolytic stability, indicates potential for efficient TcO4- removal. The structure incorporating ReO4- reveals that the supramolecular framework undergoes adaptive reconstruction facilitating the effective accommodation of TcO4-/ReO4-. The results highlight opportunities for development of soft anion-adaptive sorbents for highly selective anion decontamination.

| S-EPMC6449352 | biostudies-literature

Structural features of the oxidonitridophosphates K3 M III(PO3)3N (M III = Al, Ga).

Project description:Cubic crystals of tripotassium aluminium (or gallium) nitridotriphosphate, K3 M III(PO3)3N (M III = Al, Ga), were grown by application of the self-flux method. In their isostructural crystal structures, all metal cations and the N atom occupy special positions with site symmetry 3, while the P and O atoms are situated in general positions. The three-dimensional framework of these oxidonitridophosphates is built up from [M IIIO6] octa-hedra linked together via (PO3)3N groups. The latter are formed from three PO3N tetra-hedra sharing a common N atom. The coordination environments of the three potassium cations are represented by two types of polyhedra, viz. KO9 for one and KO9N for the other two cations. An unusual tetra-dentate type of coordination for the latter potassium cations by the (PO3)3N6- anion is observed. These K3 M III(PO3)3N (M III = Al, Ga) compounds are isostructural with the Na3 M III(PO3)3N (M III = Al, V, Ti) compounds.

| S-EPMC8647754 | biostudies-literature

An Acylhydrazone-Based Fluorescent Sensor for Sequential Recognition of Al3+ and H2PO4.

Project description:A novel acylhydrazone-based fluorescent sensor NATB was designed and synthesized for consecutive sensing of Al3+ and H2PO4-. NATB displayed fluorometric sensing to Al3+ and could sequentially detect H2PO4- by fluorescence quenching. The limits of detection for Al3+ and H2PO4- were determined to be 0.83 and 1.7 μM, respectively. The binding ratios of NATB to Al3+ and NATB-Al3+ to H2PO4- were found to be 1:1. The sequential recognition of Al3+ and H2PO4- by NATB could be repeated consecutively. In addition, the practicality of NATB was confirmed with the application of test strips. The sensing mechanisms of Al3+ and H2PO4- by NATB were investigated through fluorescence and UV-Visible spectroscopy, Job plot, ESI-MS, 1H NMR titration, and DFT calculations.

| S-EPMC8585233 | biostudies-literature

Three new acid M+ arsenates and phosphates with multiply protonated As/PO4 groups.

Project description:The crystal structures of caesium dihydrogen arsenate(V) bis[trihydrogen arsenate(V)], Cs(H2AsO4)(H3AsO4)2, ammonium dihydrogen arsenate(V) trihydrogen arsenate(V), NH4(H2AsO4)(H3AsO4), and dilithium bis(dihydrogen phosphate), Li2(H2PO4)2, were solved from single-crystal X-ray diffraction data. NH4(H2AsO4)(H3AsO4), which was hydrothermally synthesized (T = 493 K), is homeotypic with Rb(H2AsO4)(H3AsO4), while Cs(H2AsO4)(H3AsO4)2 crystallizes in a novel structure type and Li2(H2PO4)2 represents a new polymorph of this composition. The Cs and Li compounds grew at room temperature from highly acidic aqueous solutions. Li2(H2PO4)2 forms a three-dimensional (3D) framework of PO4 tetrahedra sharing corners with Li2O6 dimers built of edge-sharing LiO4 groups, which is reinforced by hydrogen bonds. The two arsenate compounds are characterized by a 3D network of AsO4 groups that are connected solely via multiple strong hydrogen bonds. A statistical evaluation of the As-O bond lengths in singly, doubly and triply protonated AsO4 groups gave average values of 1.70 (2) Å for 199 As-OH bonds, 1.728 (19) Å for As-OH bonds in HAsO4 groups, 1.714 (12) Å for As-OH bonds in H2AsO4 groups and 1.694 (16) Å for As-OH bonds in H3AsO4 groups, and a grand mean value of 1.667 (18) Å for As-O bonds to nonprotonated O atoms.

| S-EPMC6681722 | biostudies-literature

Selective Anion Extraction and Recovery Using a FeII4 L4 Cage.

Project description:Selective anion extraction is useful for the recovery and purification of valuable chemicals, and in the removal of pollutants from the environment. Here we report that FeII4 L4 cage 1 is able to extract an equimolar amount of ReO4- , a high-value anion and a nonradioactive surrogate of TcO4- , from water into nitromethane. Importantly, the extraction was efficiently performed even in the presence of 10 other common anions in water, highlighting the high selectivity of 1 for ReO4- . The extracted guest could be released into water as the cage disassembled in ethyl acetate, and then 1 could be recycled by switching the solvent to acetonitrile. The versatile solubility of the cage also enabled complete extraction of ReO4- (as the tetrabutylammonium salt) from an organic phase into water by using the sulfate salt of 1 as the extractant.

| S-EPMC6001518 | biostudies-literature

Recognition of V3+/V4+/V5+ Multielectron Reactions in Na3V(PO4)2: A Potential High Energy Density Cathode for Sodium-Ion Batteries.

Project description:Na3V(PO4)2 was reported recently as a novel cathode material with high theoretical energy density for Sodium-ion batteries (SIBs). However, whether V3+/V4+/V5+ multielectron reactions can be realized during the charging process is still an open question. In this work, Na3V(PO4)2 is synthesized by using a solid-state method. Its atomic composition and crystal structure are verified by X-ray diffraction (XRD) and neutron diffraction (ND) joint refinement. The electrochemical performance of Na3V(PO4)2 is evaluated in two different voltage windows, namely 2.5-3.8 and 2.5-4.3 V. 51V solid-state NMR (ssNMR) results disclose the presence of V5+ in Na2-xV(PO4)2 when charging Na3V(PO4)2 to 4.3 V, confirming Na3V(PO4)2 is a potential high energy density cathode through realization of V3+/V4+/V5+ multielectron reactions.

| S-EPMC7070626 | biostudies-literature

Cs[Cl3 F10 ]: A Propeller-Shaped [Cl3 F10 ]- Anion in a Peculiar A[5] B[5] Structure Type.

Project description:Reaction of CsF with ClF3 leads to Cs[Cl3 F10 ]. It contains a molecular, propeller-shaped [Cl3 F10 ]- anion with a central μ3 -F atom and three T-shaped ClF3 molecules coordinated to it. This anion represents the first example of a heteropolyhalide anion of higher ClF3 content than [ClF4 ]- and is the first Cl-containing interhalogen species with a μ-bridging F atom. The chemical bonds to the central μ3 -F atom are highly ionic and quite weak as the bond lengths within the coordinating XF3 units (X = Cl, and also calculated for Br, I) are almost unchanged in comparison to free XF3 molecules. Cs[Cl3 F10 ] crystallizes in a very rarely observed A[5] B[5] structure type, where cations and anions are each pseudohexagonally close packed, and reside, each with coordination number five, in the trigonal bipyramidal voids of the other.

| S-EPMC7589245 | biostudies-literature

Al(ORF)3 (RF = C(CF3)3) activated silica: a well-defined weakly coordinating surface anion.

Project description:Weakly Coordinating Anions (WCAs) containing electron deficient delocalized anionic fragments that are reasonably inert allow for the isolation of strong electrophiles. Perfluorinated borates, perfluorinated aluminum alkoxides, and halogenated carborane anions are a few families of WCAs that are commonly used in synthesis. Application of similar design strategies to oxide surfaces is challenging. This paper describes the reaction of Al(ORF)3*PhF (RF = C(CF3)3) with silica partially dehydroxylated at 700 °C (SiO2-700) to form the bridging silanol [triple bond, length as m-dash]Si-OH⋯Al(ORF)3 (1). DFT calculations using small clusters to model 1 show that the gas phase acidity (GPA) of the bridging silanol is 43.2 kcal mol-1 lower than the GPA of H2SO4, but higher than the strongest carborane acids, suggesting that deprotonated 1 would be a WCA. Reactions of 1 with NOct3 show that 1 forms weaker ion-pairs than classical WCAs, but stronger ion-pairs than carborane or borate anions. Though 1 forms stronger ion-pairs than these state-of-the-art WCAs, 1 reacts with alkylsilanes to form silylium type surface species. To the best of our knowledge, this is the first example of a silylium supported on derivatized silica.

| S-EPMC8148071 | biostudies-literature

Upconversion luminescence and favorable temperature sensing performance of eulytite-type Sr3Y(PO4)3:Yb3+/Ln3+ phosphors (Ln=Ho, Er, Tm).

Project description:Phase-pure eulytite-type Sr3Y0.88(PO4)3:0.10Yb3+,0.02Ln3+ upconversion (UC) phosphors (Ln = Ho, Er, Tm) were synthesized via gel-combustion and subsequent calcination at 1250°C. Their UC luminescence, temperature-dependent fluorescence intensity ratio of thermally and/or non-thermally coupled energy levels, and performance of optical temperature sensing were systematically investigated. The phosphors typically exhibit green, orange-red and blue luminescence under 978 nm NIR laser excitation for Ln = Er, Ho and Tm, respectively, which were discussed from two- and three-photon processes. The 524 nm green (Er3+), 657 nm red (Ho3+) and 476 nm blue (Tm3+) main emissions were analyzed to have average decay times of ~52 ± 2, 260.6 ± 0.7 and 117 ± 1 ?s, respectively. It was shown that (1) the Er3+ doped phosphor has a better overall performance of temperature sensing with thermally coupled 2H11/2 and 4S3/2 energy levels, whose maximum absolute (S A) and relative (SR ) sensitivities are ~5.07 × 10-3 K-1 at 523 K and ~1.16% at 298 K, respectively; (2) the Ho3+ doped phosphor shows maximum S A and SR values of ~0.019 K-1 (298-573 K) and 0.42% at 573 K for the non-thermally coupled energy pairs of 5F5/(5F4,5S2) and 5I4/5F5, respectively; (3) the Tm3+ doped phosphor has a maximum S A of ~12.74 × 10-3 K-1 at 573 K for the non-thermally coupled 3F2,3/1G4 energy levels and a maximum SR of ~1.74% K-1 at 298 K for the thermally coupled 3F2,3/3H4 levels. Advantages of the current phosphors in optical temperature sensing were also revealed by comparing with other typical UC phosphors.

| S-EPMC6764385 | biostudies-literature