Gas Permeation Characteristics of TiO₂-ZrO₂-Aromatic Organic Chelating Ligand (aOCL) Composite Membranes.

ABSTRACT: Methyl gallate (MG) and ethyl ferulate (EF) with a benzene ring were separately used as aromatic organic chelating ligands (aOCLs) to prepare two versions of TiO₂-ZrO₂-aOCL composite sols via hydrolysis and polycondensation reactions with titanium(IV) isopropoxide (Ti(OC₃H₇)₄) and zirconium(IV) butoxide (Zr(OC₄H₉)₄). Thermogravimetric and FT-IR analysis of dry gels revealed that aromatic rings were present in the residual organic matter when the gel was fired under nitrogen at 300 °C. In X-ray diffraction (XRD) measurements, the TiO₂-ZrO₂ composite material prepared using these two aOCLs showed an amorphous structure with no crystalline peaks for TiO₂ and ZrO₂. In N₂ adsorption/desorption measurements at 77 K, the TiO₂-ZrO₂ samples using the aOCLs as a template appeared porous with a larger specific surface area than TiO₂-ZrO₂ without aOCL. TiO₂-ZrO₂-aOCL composite membranes were prepared by coating and firing TiO₂-ZrO₂-aOCL sol onto a SiO₂ intermediate layer using an ?-alumina porous tube as a substrate. Compared with the TiO₂-ZrO₂ membrane, the TiO₂-ZrO₂-aOCL membranes had higher gas permselectivity. The TiO₂-ZrO₂-EF membrane showed a He permeance of 2.69 × 10^-6 mol m^-2 s^-1 Pa^-1 with permeance ratios of He/N₂ = 10.6 and He/CF₄ = 163, while the TiO₂-ZrO₂-MG membrane revealed a bit less He permeance at 8.56 × 10^-7 mol m^-2 s^-1 Pa^-1 with greater permeance ratios of He/N₂ = 61.7 and He/CF₄ = 209 at 200 °C. A microporous TiO₂-ZrO₂ amorphous structure was obtained by introducing aOCL. The differences in the side chains of each aOCL could possibly account for the differences in the microporous structures of the resultant TiO₂-ZrO₂-aOCL membranes.

SUBMITTER: Tachibana T 

PROVIDER: S-EPMC7760951 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature