Effect of Particle Size and Crystal Surface of CeO₂ on the Catalytic Combustion of Benzene.

ABSTRACT: In this study, three kinds of CeO₂ were synthesized, and supported PdO_x (x = 0,1) catalysts were prepared for benzene catalytic combustion. The samples were characterized by XRD, N₂ adsorption/desorption, HRTEM, XPS and H₂-TPR. The results show that three kinds of CeO₂ with different structures can be formed by different preparation methods. This is mainly reflected in the differences in pore structure, particle size and crystal plane. CeO₂-DC obtained from directly calcined Ce(NO₃)₃·6H₂O had the largest pore volume and pore diameter and smallest particle size. CeO₂-DC was mainly exposed to the (200) plane. Combined with the results of the ability test, it could be concluded that when Pd²⁺ and Pd⁰ exist at the same time, the activity increases with an increase in the proportion of Pd²⁺. Meanwhile, the structure of CeO₂ affects the formation of oxygen vacancies, thereby affecting the adsorption and degradation of benzene. This article reveals that the particle size, crystal planes, oxygen vacancies and proportion of Pd²⁺ have a great impact on the catalytic combustion of benzene and allow a more comprehensive understanding of the structure-activity relationship, which can guide us to design high-efficiency catalysts targeted to obtain suitable CeO₂-based catalysts for the catalytic combustion of benzene.

SUBMITTER: Wang Z 

PROVIDER: S-EPMC7766107 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature