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Effects of Weak Electrolytes on Electric Double Layer Ion Distributions.

ABSTRACT: Many common experimental systems have electric double layers containing weak electrolytes, including systems with buffers. The pH at the boundary of the diffuse layer is an important parameter for determining the physicochemical state of the system, including surface charge density. We show that the Boltzmann equilibrium relation can be used as an exact solution for weak electrolyte electric double layers. Using these results, we provide a closed-form relation for the maximum pH change in a buffered electric double layer, in terms of the boundary potential. Importantly, our results suggest that equilibrium electric double layer concepts developed for strong electrolytes can be expanded to include weak electrolytes.

SUBMITTER: Chamberlayne CF

PROVIDER: S-EPMC7780853 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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Effects of Weak Electrolytes on Electric Double Layer Ion Distributions.

Chamberlayne Christian F CF Zare Richard N RN Santiago Juan G JG

The journal of physical chemistry letters 20200918 19

Many common experimental systems have electric double layers containing weak electrolytes, including systems with buffers. The pH at the boundary of the diffuse layer is an important parameter for determining the physicochemical state of the system, including surface charge density. We show that the Boltzmann equilibrium relation can be used as an exact solution for weak electrolyte electric double layers. Using these results, we provide a closed-form relation for the maximum pH change in a buff ...[more]

PMID: 32915583

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