Enhanced photocatalytic degradation of organic dyes by ultrasonic-assisted electrospray TiO₂/graphene oxide on polyacrylonitrile/?-cyclodextrin nanofibrous membranes.

ABSTRACT: Polyacrylonitrile (PAN)/?-cyclodextrin (?-CD) composite nanofibrous membranes immobilized with nano-titanium dioxide (TiO₂) and graphene oxide (GO) were prepared by electrospinning and ultrasonic-assisted electrospinning. Scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), and X-ray diffraction (XRD) confirmed that TiO₂ and GO were more evenly dispersed on the surface and inside of the nanofibers after 45 min of ultrasonic treatment. Adding TiO₂ and GO reduced the fiber diameter; the minimum fiber diameter was 84.66 ± 40.58 nm when the mass ratio of TiO₂-to-GO was 8:2 (PAN/?-CD nanofibrous membranes was 191.10 ± 45.66 nm). Using the anionic dye methyl orange (MO) and the cationic dye methylene blue (MB) as pollutant models, the photocatalytic activity of the nanofibrous membrane under natural sunlight was evaluated. It was found that PAN/?-CD/TiO₂/GO composite nanofibrous membrane with an 8:2 mass ratio of TiO₂-to-GO exhibited the best degradation efficiency for the dyes. The degradation efficiency for MB and MO were 93.52 ± 1.83% and 90.92 ± 1.52%, respectively. Meanwhile, the PAN/?-CD/TiO₂/GO composite nanofibrous membrane also displayed good antibacterial properties and the degradation efficiency for MB and MO remained above 80% after 3 cycles. In general, the PAN/?-CD/TiO₂/GO nanofibrous membrane is eco-friendly, reusable, and has great potential for the removal of dyes from industrial wastewaters.

SUBMITTER: Zhang R 

PROVIDER: S-EPMC7786584 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature