Unknown

Dataset Information

0

A four-electron Zn-I2 aqueous battery enabled by reversible I-/I2/I+ conversion.


ABSTRACT: Electrochemically reversible redox couples that embrace more electron transfer at a higher potential are the eternal target for energy storage batteries. Here, we report a four-electron aqueous zinc-iodine battery by activating the highly reversible I2/I+ couple (1.83?V vs. Zn/Zn2+) in addition to the typical I-/I2 couple (1.29?V). This is achieved by intensive solvation of the aqueous electrolyte to yield ICl inter-halogens and to suspend its hydrolysis. Experimental characterization and modelling reveal that limited water activity and sufficient free chloride ions in the electrolyte are crucial for the four-electron process. The merits of the electrolyte also afford to stabilize Zn anode, leading to a reliable Zn-I2 aqueous battery of 6000 cycles. Owing to high operational voltage and capacity, energy density up to 750?Wh?kg-1 based on iodine mass was achieved (15-20?wt% iodine in electrode). It pushes the Zn-I2 battery to a superior level among these available aqueous batteries.

SUBMITTER: Zou Y 

PROVIDER: S-EPMC7794333 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature

altmetric image

Publications

A four-electron Zn-I<sub>2</sub> aqueous battery enabled by reversible I<sup>-</sup>/I<sub>2</sub>/I<sup>+</sup> conversion.

Zou Yiping Y   Liu Tingting T   Du Qijun Q   Li Yingying Y   Yi Haibo H   Zhou Xing X   Li Zhuxin Z   Gao Lujie L   Zhang Lan L   Liang Xiao X  

Nature communications 20210108 1


Electrochemically reversible redox couples that embrace more electron transfer at a higher potential are the eternal target for energy storage batteries. Here, we report a four-electron aqueous zinc-iodine battery by activating the highly reversible I<sub>2</sub>/I<sup>+</sup> couple (1.83 V vs. Zn/Zn<sup>2+</sup>) in addition to the typical I<sup>-</sup>/I<sub>2</sub> couple (1.29 V). This is achieved by intensive solvation of the aqueous electrolyte to yield ICl inter-halogens and to suspend i  ...[more]

Similar Datasets

| S-EPMC7770770 | biostudies-literature
| S-EPMC7770836 | biostudies-literature
| S-EPMC10834454 | biostudies-literature
| S-EPMC8229935 | biostudies-literature
| S-EPMC10581958 | biostudies-literature
| S-EPMC7709974 | biostudies-literature
| S-EPMC7770901 | biostudies-literature
| S-EPMC8397361 | biostudies-literature
| S-EPMC10796916 | biostudies-literature
| S-EPMC8292880 | biostudies-literature