Tailoring of a visible-light-absorbing biaxial ferroelectric towards broadband self-driven photodetection.

ABSTRACT: In terms of strong light-polarization coupling, ferroelectric materials with bulk photovoltaic effects afford a promising avenue for optoelectronic devices. However, due to severe polarization deterioration caused by leakage current of photoexcited carriers, most of ferroelectrics are merely capable of absorbing 8-20% of visible-light spectra. Ferroelectrics with the narrow bandgap (<2.0?eV) are still scarce, hindering their practical applications. Here, we present a lead-iodide hybrid biaxial ferroelectric, (isopentylammonium)₂(ethylammonium)₂Pb₃I₁₀, which shows large spontaneous polarization (~5.2??C/cm²) and a narrow direct bandgap (~1.80?eV). Particularly, the symmetry breaking of 4/mmmFmm2 species results in its biaxial attributes, which has four equivalent polar directions. Accordingly, exceptional in-plane photovoltaic effects are exploited along the crystallographic [001] and [010] axes directions inside the crystallographic bc-plane. The coupling between ferroelectricity and photovoltaic effects endows great possibility toward self-driven photodetection. This study sheds light on future optoelectronic device applications.

SUBMITTER: Han S 

PROVIDER: S-EPMC7804191 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature