Seeded Growth Combined with Cation Exchange for the Synthesis of Anisotropic Cu_2-x S/ZnS, Cu_2-x S, and CuInS₂ Nanorods.

ABSTRACT: Colloidal copper(I) sulfide (Cu_2-x S) nanocrystals (NCs) have attracted much attention for a wide range of applications because of their unique optoelectronic properties, driving scientists to explore the potential of using Cu_2-x S NCs as seeds in the synthesis of heteronanocrystals to achieve new multifunctional materials. Herein, we developed a multistep synthesis strategy toward Cu_2-x S/ZnS heteronanorods. The Janus-type Cu_2-x S/ZnS heteronanorods are obtained by the injection of hexagonal high-chalcocite Cu_2-x S seed NCs in a hot zinc oleate solution in the presence of suitable surfactants, 20 s after the injection of sulfur precursors. The Cu_2-x S seed NCs undergo rapid aggregation and coalescence in the first few seconds after the injection, forming larger NCs that act as the effective seeds for heteronucleation and growth of ZnS. The ZnS heteronucleation occurs on a single (100) facet of the Cu_2-x S seed NCs and is followed by fast anisotropic growth along a direction that is perpendicular to the c-axis, thus leading to Cu_2-x S/ZnS Janus-type heteronanorods with a sharp heterointerface. Interestingly, the high-chalcocite crystal structure of the injected Cu_2-x S seed NCs is preserved in the Cu_2-x S segments of the heteronanorods because of the high-thermodynamic stability of this Cu_2-x S phase. The Cu_2-x S/ZnS heteronanorods are subsequently converted into single-component Cu_2-x S and CuInS₂ nanorods by postsynthetic topotactic cation exchange. This work expands the possibilities for the rational synthesis of colloidal multicomponent heteronanorods by allowing the design principles of postsynthetic heteroepitaxial seeded growth and nanoscale cation exchange to be combined, yielding access to a plethora of multicomponent heteronanorods with diameters in the quantum confinement regime.

SUBMITTER: Xia C 

PROVIDER: S-EPMC7808334 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature