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SC-SC Anion-Assisted Linker Exchange within a Three-Dimensional Cu(II)-Triazole Framework: A Luminescent Probe for S2.


ABSTRACT: A three-dimensional (3D) binodal 3,5-connected net, {[Cu(MTP)(H2O)](NO3)}n (1) with the Schläfli symbol of {3·72}{32·75·83} can be transformed into a two-dimensional (2D) kagóme network with the Schlafli symbol of {32·62·72} in an irreversible single crystal-single crystal (SC-SC) guest-assisted linker exchange process. The product of this SC-SC represents the first luminescent probe for S2- based on triazole ligand.

SUBMITTER: Wang Y 

PROVIDER: S-EPMC7818306 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature

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SC-SC Anion-Assisted Linker Exchange within a Three-Dimensional Cu(II)-Triazole Framework: A Luminescent Probe for S<sup>2</sup>.

Wang Ying Y   Gong Shuang-Shuang SS   Liu Yue Y   Cheng Lin L   Li Shuang-Shuang SS   Zhang Ying Y   Cui Yukun Y   Liang Chenlu C   Tang Li L   Ren Peng P   Fang Yu Y   Day Gregory S GS  

ACS omega 20210107 2


A three-dimensional (3D) binodal 3,5-connected net, {[Cu(MTP)(H<sub>2</sub>O)](NO<sub>3</sub>)}<sub>n</sub> (<b>1</b>) with the Schläfli symbol of {3·7<sup>2</sup>}{3<sup>2</sup>·7<sup>5</sup>·8<sup>3</sup>} can be transformed into a two-dimensional (2D) kagóme network with the Schlafli symbol of {3<sup>2</sup>·6<sup>2</sup>·7<sup>2</sup>} in an irreversible single crystal-single crystal (SC-SC) guest-assisted linker exchange process. The product of this SC-SC represents the first luminescent pr  ...[more]

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