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Mechanistic origin and unlocking of negative capacitance in perovskites solar cells.

ABSTRACT: We have unlocked the mechanistic behavior of negative capacitance in perovskite solar cells (PSCs) by analyzing impedance spectra at variable photovoltage and applied bias, temperature-dependent capacitance versus frequency (C-f) spectra, and current-voltage (J-V) characteristics. We noted that p-i-n type PSCs having PEDOT:PSS or PTAA as hole transport layer display negative capacitance feature at low and intermediate frequencies. The activation energies (E _a ) for the observance of negative capacitance were found to be in a similar order of magnitude required for the ionic migration. Moreover, the kinetic relaxation time (? _kin ) estimated to be in the same order of magnitude required to activate the halide ion migration. Our investigation suggests that the primary reason for the appearance of negative capacitance in PSCs with a p-i-n configuration is associated with the migration of halide ions and vacancies in the perovskite layers.

SUBMITTER: Khan MT

PROVIDER: S-EPMC7820557 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature

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Mechanistic origin and unlocking of negative capacitance in perovskites solar cells.

Khan Mohd Taukeer MT Huang Peng P Almohammedi Abdullah A Kazim Samrana S Ahmad Shahzada S

iScience 20201231 2

We have unlocked the mechanistic behavior of negative capacitance in perovskite solar cells (PSCs) by analyzing impedance spectra at variable photovoltage and applied bias, temperature-dependent capacitance versus frequency (C-f) spectra, and current-voltage (J-V) characteristics. We noted that p-i-n type PSCs having PEDOT:PSS or PTAA as hole transport layer display negative capacitance feature at low and intermediate frequencies. The activation energies (E a< ...[more]

PMID: 33521597

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