Reduced Graphene Oxide Aerogel inside Melamine Sponge as an Electrocatalyst for the Oxygen Reduction Reaction.

ABSTRACT: A graphene oxide aerogel (GOA) was formed inside a melamine sponge (MS) framework. After reduction with hydrazine at 60 °C, the electrical conductive nitrogen-enriched rGOA-MS composite material with a specific density of 20.1 mg/cm³ was used to fabricate an electrode, which proved to be a promising electrocatalyst for the oxygen reduction reaction. The rGOA-MS composite material was characterized by elemental analysis, scanning electron microscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy. It was found that nitrogen in the material is presented by different types with the maximum concentration of pyrrole-like nitrogen. By using Raman scattering it was established that the rGOA component of the material is graphene-like carbon with an average size of the sp²-domains of 5.7 nm. This explains a quite high conductivity of the composite obtained.

SUBMITTER: Manzhos RA 

PROVIDER: S-EPMC7827904 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature