Ontology highlight
ABSTRACT:
SUBMITTER: Haldar R
PROVIDER: S-EPMC7839528 | biostudies-literature | 2020 Dec
REPOSITORIES: biostudies-literature
Haldar Ritesh R Jakoby Marius M Kozlowska Mariana M Rahman Khan Motiur M Chen Hongye H Pramudya Yohanes Y Richards Bryce S BS Heinke Lars L Wenzel Wolfgang W Odobel Fabrice F Diring Stéphane S Howard Ian A IA Lemmer Uli U Wöll Christof C
Chemistry (Weinheim an der Bergstrasse, Germany) 20201117 71
Several photophysical properties of chromophores depend crucially on intermolecular interactions. Thermally-activated delayed fluorescence (TADF) is often influenced by close packing of the chromophore assembly. In this context, the metal-organic framework (MOF) approach has several advantages: it can be used to steer aggregation such that the orientation within aggregated structures can be predicted using rational approaches. We demonstrate this design concept for a DPA-TPE (diphenylamine-tetra ...[more]