Ontology highlight
ABSTRACT:
SUBMITTER: Hanau K
PROVIDER: S-EPMC7839700 | biostudies-literature | 2021 Jan
REPOSITORIES: biostudies-literature
Hanau Katharina K Schwan Sebastian S Schäfer Moritz R MR Müller Marius J MJ Dues Christof C Rinn Niklas N Sanna Simone S Chatterjee Sangam S Mollenhauer Doreen D Dehnen Stefanie S
Angewandte Chemie (International ed. in English) 20201215 3
We report the extension of the class of organotetrel sulfide clusters with further examples of the still rare silicon-based species, synthesized from RSiCl<sub>3</sub> with R=phenyl (Ph, I), naphthyl (Np, II), and styryl (Sty, III) with Na<sub>2</sub> S. Besides known [(PhSi)<sub>4</sub> S<sub>6</sub> ] (IV), new compounds [(NpSi)<sub>4</sub> S<sub>6</sub> ] (1) and [(StySi)<sub>4</sub> S<sub>6</sub> ] (2) were obtained, the first two of which underwent reactions with [AuCl(PPh<sub>3</sub> )] to ...[more]