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Cold Sintering of Calcium Carbonate for Construction Material Applications.

ABSTRACT: An alternative to traditional binder-based construction materials using "cold sintering", a hydrothermal mechanism that involves subjecting the sample to simultaneous pressure and comparatively low temperatures, was explored. Ground and precipitate calcium carbonates (GCC and PCC) were used as the primary starting materials. Ordinary portland cement (OPC) and zinc oxide were studied for comparison. Compressive strength tests showed promising results from the OPC mortars with the cement mostly replaced by GCC. Scanning electron microscopy showed sintering of calcium carbonate and zinc oxide with the selection of suitable solutions. Porosity of sintered samples measured by nitrogen adsorption-desorption improved considerably. These data support the feasibility of cold sintering as an alternative method for production of conventional precast construction materials.

SUBMITTER: Zahabi M

PROVIDER: S-EPMC7859949 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature

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Cold Sintering of Calcium Carbonate for Construction Material Applications.

Zahabi Mehrzad M Said Aly A Memari Ali A

ACS omega 20210112 4

An alternative to traditional binder-based construction materials using "cold sintering", a hydrothermal mechanism that involves subjecting the sample to simultaneous pressure and comparatively low temperatures, was explored. Ground and precipitate calcium carbonates (GCC and PCC) were used as the primary starting materials. Ordinary portland cement (OPC) and zinc oxide were studied for comparison. Compressive strength tests showed promising results from the OPC mortars with the cement mostly re ...[more]

PMID: 33553876

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Project description:RationaleThe stable carbon isotopic (δ13 C) reference material (RM) LSVEC Li2 CO3 has been found to be unsuitable for δ13 C standardization work because its δ13 C value increases with exposure to atmospheric CO2 . A new CaCO3 RM, USGS44, has been prepared to alleviate this situation.MethodsUSGS44 was prepared from 8 kg of Merck high-purity CaCO3 . Two sets of δ13 C values of USGS44 were determined. The first set of values was determined by online combustion, continuous-flow (CF) isotope-ratio mass spectrometry (IRMS) of NBS 19 CaCO3 (δ13 CVPDB = +1.95 milliurey (mUr) exactly, where mUr = 0.001 = 1‰), and LSVEC Li2 CO3 (δ13 CVPDB = -46.6 mUr exactly), and normalized to the two-anchor δ13 CVPDB-LSVEC isotope-delta scale. The second set of values was obtained by dual-inlet (DI)-IRMS of CO2 evolved by reaction of H3 PO4 with carbonates, corrected for cross contamination, and normalized to the single-anchor δ13 CVPDB scale.ResultsUSGS44 is stable and isotopically homogeneous to within 0.02 mUr in 100-μg amounts. It has a δ13 CVPDB-LSVEC value of -42.21 ± 0.05 mUr. Single-anchor δ13 CVPDB values of -42.08 ± 0.01 and -41.99 ± 0.02 mUr were determined by DI-IRMS with corrections for cross contamination.ConclusionsThe new high-purity, well-homogenized calcium carbonate isotopic reference material USGS44 is stable and has a δ13 CVPDB-LSVEC value of -42.21 ± 0.05 mUr for both EA/IRMS and DI-IRMS measurements. As a carbonate relatively depleted in 13 C, it is intended for daily use as a secondary isotopic reference material to normalize stable carbon isotope delta measurements to the δ13 CVPDB-LSVEC scale. It is useful in quantifying drift with time, determining mass-dependent isotopic fractionation (linearity correction), and adjusting isotope-ratio-scale contraction. Due to its fine grain size (smaller than 63 μm), it is not suitable as a δ18 O reference material. A δ13 CVPDB-LSVEC value of -29.99 ± 0.05 mUr was determined for NBS 22 oil.

Dataset Information

Cold Sintering of Calcium Carbonate for Construction Material Applications.

Publications

Cold Sintering of Calcium Carbonate for Construction Material Applications.

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