Ontology highlight
ABSTRACT:
SUBMITTER: Sandineni P
PROVIDER: S-EPMC7866034 | biostudies-literature | 2021 Jan
REPOSITORIES: biostudies-literature
Molecules (Basel, Switzerland) 20210124 3
Herein, we report the syntheses of two lithium-vanadium oxide-fluoride compounds crystallized from the same reaction mixture through a time variation experiment. A low temperature hydrothermal route employing a viscous paste of V<sub>2</sub>O<sub>5</sub>, oxalic acid, LiF, and HF allowed the crystallization of one metastable phase initially, Li<sub>2</sub>VO<sub>0.55</sub>(H<sub>2</sub>O)<sub>0.45</sub>F<sub>5</sub>⋅2H<sub>2</sub>O (<b>I</b>), which on prolonged heating transforms to a chemicall ...[more]