Ontology highlight
ABSTRACT:
SUBMITTER: Zhan YZ
PROVIDER: S-EPMC7876002 | biostudies-literature | 2021 Feb
REPOSITORIES: biostudies-literature
Nature communications 20210210 1
The development of straightforward synthesis of regio- and stereodefined alkenes with multiple aliphatic substituents under mild conditions is an unmet challenge owing to competitive β-hydride elimination and selectivity issues. Herein, we report the nickel-catalyzed intermolecular cross-dialkylation of alkynes devoid of directing or activating groups to afford multiple aliphatic substituted alkenes in a syn-selective fashion at room temperature. The combination of two-electron oxidative cyclome ...[more]